Non-enzymic beta-decarboxylation of aspartic acid.
作者： V. M. Doctor , J. Oro'
DOI: 10.1007/BF01653961
关键词: Biology 、 Metal ions in aqueous solution 、 Biochemistry 、 Catalysis 、 Transamination 、 Aspartic acid 、 Pyridoxal 、 Medicinal chemistry 、 Oxalic acid 、 Alanine 、 Decarboxylation
摘要: Non-enzymicβ-decarboxylation of aspartic acid at 85° is catalyzed by Al3+ and pyridoxal. The reaction optimum pH 4.0. Both pyridoxal are specifically required because replacing these other cations or vitamin B6 derivatives greatly lowers the formation alanine. Conversion 8 µmoles to alanine in presence 1µmole 5 Increasing concentration more than latter being converted pyruvate transamination with excess
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