Layered double hydroxides intercalated with borate: effect of fertilization on boron leaching and successive sunflower cultivations

作者: Gustavo Franco de Castro , Jader Alves Ferreira , Lincoln Zotarelli , Edson Marcio Mattiello , Roberto Ferreira Novais

DOI: 10.1039/C9NJ04952E

关键词: FertilizerNuclear chemistryBoric acidIncubationChemistryLeaching (agriculture)BoraxBoronSunflowerLayered double hydroxides

摘要: Boron (B) can easily leach into the soil when added in form of a soluble fertilizer such as borax or boric acid (H3BO3); however, large quantities B cause toxicity plants. The use slow release source layered double hydroxides intercalated with borate may minimize leaching/toxicity B. objectives this study are to evaluate availability and leaching from magnesium–aluminium anions (Mg2Al-B-LDH) H3BO3 sandy soil, bioavailability these two sources consecutive cultivations sunflower. Mg2Al-B-LDH at rates (10 20 mg dm−3 B) were incubated for 1, 2, 3, 5, 10, 40 days. After incubation, was evaluated using hot-water extraction method. For study, incorporated top 0.5 cm 15, 20, 25 30 days before water volume equivalent total soil-pore space. Sunflower plants cultivated seasons greenhouse six (0, 0.5, 3 5 dm−3) factorial 2 × 6, four replicates. Plants received single application sowing first cultivation. had greater than regardless applied rate time incubation. by resulted significant reduction leached compared H3BO3. There quadratic linear response sunflower aboveground biomass accumulation increasing Mg2Al-B-LDH, respectively, second cultivation only. A boron plant toxicity, while promoted throughout period.

参考文章(25)
Margaret Abat, Fien Degryse, Roslyn Baird, Michael J. McLaughlin, Slow-release boron fertilisers: co-granulation of boron sources with mono-ammonium phosphate (MAP) Soil Research. ,vol. 53, pp. 505- 511 ,(2015) , 10.1071/SR14128
Kallol Bhattacharyya, Jajati Mandal, Hirak Banerjee, Ayon Alipatra, Krishnendu Ray, Amit Phonglosa, Boron Fertilization in Sunflower (Helianthus annuusL.) in an Inceptisol of West Bengal, India Communications in Soil Science and Plant Analysis. ,vol. 46, pp. 528- 544 ,(2015) , 10.1080/00103624.2014.997389
Myong A. Woo, Tae Woo Kim, Mi-Jeong Paek, Hyung-Wook Ha, Jin-Ho Choy, Seong-Ju Hwang, Phosphate-intercalated Ca–Fe-layered double hydroxides: Crystal structure, bonding character, and release kinetics of phosphate Journal of Solid State Chemistry. ,vol. 184, pp. 171- 176 ,(2011) , 10.1016/J.JSSC.2010.11.003
Frederick L. Theiss, Godwin A. Ayoko, Ray L. Frost, Removal of boron species by layered double hydroxides: a review. Journal of Colloid and Interface Science. ,vol. 402, pp. 114- 121 ,(2013) , 10.1016/J.JCIS.2013.03.051
O. E. Anderson, Fred C. Boswell, Boron and Manganese Effects on Cotton Yield, Lint Quality, and Earliness of Harvest1 Agronomy Journal. ,vol. 60, pp. 488- 493 ,(1968) , 10.2134/AGRONJ1968.00021962006000050014X
Mohamed R. Berber, Inas H. Hafez, Keiji Minagawa, Takeshi Mori, A sustained controlled release formulation of soil nitrogen based on nitrate-layered double hydroxide nanoparticle material Journal of Soils and Sediments. ,vol. 14, pp. 60- 66 ,(2014) , 10.1007/S11368-013-0766-3
Ahmet Nedim Ay, Birgül Zümreoglu-Karan, Abidin Temel, Luis Mafra, Layered double hydroxides with interlayer borate anions: A critical evaluation of synthesis methodology and pH-independent orientations in nano-galleries Applied Clay Science. ,vol. 51, pp. 308- 316 ,(2011) , 10.1016/J.CLAY.2010.12.015
Valentim da Silva, Marcos Y. Kamogawa, Rafael Marangoni, Antonio Salvio Mangrich, Fernando Wypych, Hidróxidos duplos lamelares como matrizes para fertilizantes de liberação lenta de nitrato Revista Brasileira De Ciencia Do Solo. ,vol. 38, pp. 272- 277 ,(2014) , 10.1590/S0100-06832014000100027
Yuting Zhang, Xinhua He, Hong Liang, Jian Zhao, Yueqiang Zhang, Chen Xu, Xiaojun Shi, Long-term tobacco plantation induces soil acidification and soil base cation loss Environmental Science and Pollution Research. ,vol. 23, pp. 5442- 5450 ,(2016) , 10.1007/S11356-015-5673-2
Ahmad Imran, Sandra López-Rayo, Jakob Magid, Hans Christian Bruun Hansen, Dissolution kinetics of pyroaurite-type layered double hydroxide doped with Zn: Perspectives for pH controlled micronutrient release Applied Clay Science. ,vol. 123, pp. 56- 63 ,(2016) , 10.1016/J.CLAY.2015.12.016