CHEMICAL REACTIVITY IN ORGANIZED MEDIA : STATISTICAL ENTROPY AND INFORMATION IN CRYSTALS AND ENZYMES
DOI: 10.1016/S1359-0286(98)80052-1
关键词: Homogeneous 、 Chemical physics 、 Supramolecular chemistry 、 Work (thermodynamics) 、 Chemical reaction 、 Organic chemistry 、 Chemistry
摘要: Abstract The control of chemical reactivity has been a subject intense research activity for many years. It is known that supramolecular systems are capable influencing the outcome reactions to levels not easily achieved by homogeneous liquids. Their influence always expressed through specific interactions stabilize transition state. role can be frequently ascribed structural pre-organization reactant towards particular reactions. Because this, as diverse micelles, zeolites, enzymes and crystals referred organized media. Recent work on in media may analyzed with an intuitive model based simple statistical entropy principles.
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sci-hub.se 参考文章(52)
Jean‐Marie Lehn, Supramolecular Chemistry: Concepts and Perspectives Malta II : Frontiers of Chemical Sciences 2 : Research and Education in the Middle East, Malta. ,(1995) , 10.1002/3527607439
Physical supramolecular chemistry Springer Netherlands. ,(1996) , 10.1007/978-94-009-0317-3
V. Ramamurthy, Photochemistry in Organized and Constrained Media ,(1991)
Jean-Marie Lehn, JL Atwood, JED Davies, DD MacNicol, F Vögtle, Comprehensive Supramolecular Chemistry ,(1996)
J.R. Scheffer, M. Garcia-Garibay, Absolute Asymmetric Synthesis Via Photochemical Reactions of Chiral Crystals Studies in Surface Science and Catalysis. ,vol. 47, pp. 501- 525 ,(1989) , 10.1016/S0167-2991(08)61209-4
Jeehiun K. Lee, K. N. Houk, A proficient enzyme revisited: the predicted mechanism for orotidine monophosphate decarboxylase. Science. ,vol. 276, pp. 942- 945 ,(1997) , 10.1126/SCIENCE.276.5314.942
A Radzicka, R Wolfenden, A proficient enzyme Science. ,vol. 267, pp. 90- 93 ,(1995) , 10.1126/SCIENCE.7809611
Brian G. Miller, Thomas W. Traut, Wolfenden, A Role for Zinc in OMP Decarboxylase, an Unusually Proficient Enzyme Journal of the American Chemical Society. ,vol. 120, pp. 2666- 2667 ,(1998) , 10.1021/JA980066I
Ronald Breslow, Xiaojun Zhang, Ying Huang, Selective Catalytic Hydroxylation of a Steroid by an Artificial Cytochrome P-450 Enzyme Journal of the American Chemical Society. ,vol. 119, pp. 4535- 4536 ,(1997) , 10.1021/JA9704951
János Rétey, Enzymic Reaction Selectivity by Negative Catalysis or How Do Enzymes Deal with Highly Reactive Intermediates Angewandte Chemie. ,vol. 29, pp. 355- 361 ,(1990) , 10.1002/ANIE.199003551