Anion-Templated Assembly of a Supramolecular Cage Complex

作者： James S. Fleming , Karen L. V. Mann , Charles-Antoine Carraz , Elefteria Psillakis , John C. Jeffery

DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q

关键词: Transition metal 、 Tetrafluoroborate 、 Cage 、 Supramolecular chemistry 、 Crystallography 、 Template synthesis 、 Chemistry 、 Self-assembly 、 Stereochemistry 、 Ion 、 Bridging ligand 、 General chemistry 、 Catalysis

摘要: The templating effect of the tetrafluoroborate ion leads to assembly four CoII ions and six bridging ligands around this anion give a tetrahedral complex with ligand along each edge trapped in central cavity (shown below). Surprisingly under identical conditions but NiII simpler dinuclear forms.