The effect of alloying with antimony on the electrochemical properties of lead
作者： R. Babić , M. Metikoš-Huković , N. Lajqy , S. Brinić
DOI: 10.1016/0378-7753(94)01925-8
关键词: Electrochemistry 、 Cyclic voltammetry 、 Redox 、 Dielectric spectroscopy 、 Oxygen evolution 、 Sulfuric acid 、 Inorganic chemistry 、 Antimony 、 Chemistry 、 Lead oxide
摘要: The electrochemical behaviour of lead, antimony and lead-antimony binary alloys has been studied as a function sulfuric acid concentrations in the lead alloy. investigation was performed by means cyclic voltammetry impedance spectroscopy methods. Cyclic voltammetry, between hydrogen oxygen evolution over narrower regions potential coupled with systematic variation scan rates positive or negative reversal potential, revealed more details on oxidation reduction processes region Pb(II)-, Pb(IV)- Sb(III)-containing species which give further insight into nature reactions lead/acid battery. measurements range oxide, takes place, show decrease film resistance increasing content.
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