Competitive Complexation of Copper and Zinc by Sequentially Extracted Humic Substances from Manure Compost
作者： Shuai LIU , Xu-dong WANG , Li-lan LU , Shi-rong DIAO , Jun-feng ZHANG
DOI: 10.1016/S1671-2927(08)60172-8
关键词: Chicken manure 、 Inorganic chemistry 、 Sodium hydroxide 、 Humus 、 Copper 、 Manure 、 Sodium 、 Compost 、 Zinc 、 Chemistry
摘要: Abstract Chicken manure with similar content of copper and zinc was chosen to conduct a composting experiment investigate the changes organic carbon humus substance complexed (HS-Cu) (HS-Zn), which were extracted by water (H2O), sodium hydroxide (NaOH), pyrophate-NaOH mixture (Na4P2O7-NaOH), sequentially. Distributions in fulvic acids (FA) humic (HA) three extracts studied. During composting, concentrations increased from about 500 mg kg−1 raw material 1 100 final products. HS-Cu H2O, NaOH, Na4P2O7-NaOH occupied 6.7, 26.7, 19% averagely total HS-Zn represented 2.7, 13.7, 17% compost, respectively. In extracts, both HA FA mainly Cu mole ratio Zn 2.8 fractions 2.6 fractions, copper, so that ratios HA-Cu HA-Zn averaged 3.4 NaOH extracts. had potential complex zinc, FA-Cu FA-Zn close 1. or zinc. The With extractable level as high HS-Cu. This indicated more stable complexes formed late decomposition period. competition between be became weaker process.
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Valtcho D. Zheljazkov, Phil R. Warman, Phytoavailability and fractionation of copper, manganese, and zinc in soil following application of two composts to four crops. Environmental Pollution. ,vol. 131, pp. 187- 195 ,(2004) , 10.1016/J.ENVPOL.2004.02.007
Seunghun Kang, Dula Amarasiriwardena, Peter Veneman, Baoshan Xing, CHARACTERIZATION OF TEN SEQUENTIALLY EXTRACTED HUMIC ACIDS AND A HUMIN FROM A SOIL IN WESTERN MASSACHUSETTS Soil Science. ,vol. 168, pp. 880- 887 ,(2003) , 10.1097/01.SS.0000106404.84926.B0
Larry M. Shuman, Organic Waste Amendments Effect on Zinc Fractions of Two Soils Journal of Environmental Quality. ,vol. 28, pp. 1442- 1447 ,(1999) , 10.2134/JEQ1999.00472425002800050008X
Jenn-Hung Hsu, Shang-Lien Lo, Effect of composting on characterization and leaching of copper, manganese, and zinc from swine manure Environmental Pollution. ,vol. 114, pp. 119- 127 ,(2001) , 10.1016/S0269-7491(00)00198-6
David J Walker, Rafael Clemente, M.Pilar Bernal, Contrasting effects of manure and compost on soil pH, heavy metal availability and growth of Chenopodium album L. in a soil contaminated by pyritic mine waste. Chemosphere. ,vol. 57, pp. 215- 224 ,(2004) , 10.1016/J.CHEMOSPHERE.2004.05.020
Paul Schwab, D. Zhu, M.K. Banks, Heavy metal leaching from mine tailings as affected by organic amendments. Bioresource Technology. ,vol. 98, pp. 2935- 2941 ,(2007) , 10.1016/J.BIORTECH.2006.10.012
Kaisa Heikkinen, Nature of dissolved organic matter in the drainage basin of a boreal humic river in Northern Finland Journal of Environmental Quality. ,vol. 19, pp. 649- 657 ,(1990) , 10.2134/JEQ1990.00472425001900040004X
Soumia Amir, Mohamed Hafidi, Georges Merlina, Jean-Claude Revel, Sequential extraction of heavy metals during composting of sewage sludge. Chemosphere. ,vol. 59, pp. 801- 810 ,(2005) , 10.1016/J.CHEMOSPHERE.2004.11.016
John Baham, Garrison Sposito, Proton and Metal Complexation by Water‐soluble Ligands Extracted from Anaerobically Digested Sewage Sludge Journal of Environmental Quality. ,vol. 15, pp. 239- 244 ,(1986) , 10.2134/JEQ1986.00472425001500030007X
Shoko Inaba, Chisato Takenaka, Effects of dissolved organic matter on toxicity and bioavailability of copper for lettuce sprouts Environment International. ,vol. 31, pp. 603- 608 ,(2005) , 10.1016/J.ENVINT.2004.10.017