Electronic structure and reactivity of propellanes : The stereochemistry of diels-alder- and related cyclo-additions in the series of [4.4.2] and [4.4.3] propellanes; models and interpretations
作者： Michael C. Böhm , Rolf G. Eiter
DOI: 10.1016/0040-4020(80)80167-0
关键词: Chemistry 、 Electronic structure 、 Computational chemistry 、 Series (mathematics) 、 Diels alder 、 Stereochemistry 、 Reactivity (chemistry)
摘要: Abstract The stereochemistry of the products obtained by Diels-Alder addition 1 to 2-6 and 14 15 has been rationalised. In case propellanes a frontier MO approach substantiated extended Huckel calculations invoked. For Coulomb interaction between polar SO SO2 groups dienophile is decisive for observed stereochemistry.
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