Microscopic models of desorption spectra
作者： W L Schaich
DOI: 10.1088/0022-3719/11/12/013
关键词: Materials science 、 Activation barrier 、 Thermodynamics 、 Physical chemistry 、 Desorption 、 Spectral line 、 Flux 、 Angle dependence 、 Adsorption
摘要: Several microscopic models of desorption reactions are studied. The emphasis is on the predicted energy and angle dependence desorbed flux. model Lennard-Jones, Devonshire, Strachan (1936) extended to three dimensions Kramers (1940) adapted a surface configuration. latter shows good qualitative agreement with experiment if it coupled an activation barrier adsorption, as suggested by Van Willigen (1968).
sci-hub.se 参考文章(27)
Società italiana di fisica, F. O. Goodman, Dynamic aspects of surface physics Editrice Compositori. ,(1974)
Frank O. Goodman, Scattering of atoms by solid surfaces: Critical review of the lennard-jones, devonshire and strachan theory of inelastic gas-surface interactions, and some improvements Surface Science. ,vol. 24, pp. 667- 699 ,(1971) , 10.1016/0039-6028(71)90294-9
Patrick J. Pagni, Comparison of diffusion theory adsorption and desorption rate constants with experimental lifetimes The Journal of Chemical Physics. ,vol. 58, pp. 2940- 2954 ,(1973) , 10.1063/1.1679602
George Comsa, Rudolf David, Klaus D. Rendulic, Velocity distribution of H 2 , HD, and D 2 molecules desorbing from polycrystalline nickel surfaces Physical Review Letters. ,vol. 38, pp. 775- 778 ,(1977) , 10.1103/PHYSREVLETT.38.775
Mary Shugard, John C. Tully, Abraham Nitzan, Dynamics of gas–solid interactions: Calculations of energy transfer and sticking The Journal of Chemical Physics. ,vol. 66, pp. 2534- 2544 ,(1977) , 10.1063/1.434249
Bernard Bendow, See-Chen Ying, Phonon-Induced Desorption of Adatoms from Crystal Surfaces. I. Formal Theory Physical Review B. ,vol. 7, pp. 622- 636 ,(1973) , 10.1103/PHYSREVB.7.622
S Holloway, P Jewsbury, J.L Beeby, Theoretical analysis of desorption from surfaces Surface Science. ,vol. 63, pp. 339- 347 ,(1977) , 10.1016/0039-6028(77)90349-1
S. A. Adelman, B. J. Garrison, Generalized Langevin theory for gas/solid processes: Dynamical solid models Journal of Chemical Physics. ,vol. 65, pp. 3751- 3761 ,(1976) , 10.1063/1.433564
W. L. Schaich, Surface properties of an itinerant paramagnet Physical Review B. ,vol. 14, pp. 1488- 1495 ,(1976) , 10.1103/PHYSREVB.14.1488
J. D. Doll, D. R. Dion, Generalized Langevin equation approach for atom/solid–surface scattering: Numerical techniques for Gaussian generalized Langevin dynamics Journal of Chemical Physics. ,vol. 65, pp. 3762- 3766 ,(1976) , 10.1063/1.433565