Widths and shifts of HF vibration-rotation absorption lines induced by pressure of rare gases☆

作者: J. Jarecki , R.M. Herman

DOI: 10.1016/0022-4073(75)90082-5

关键词: XenonRotationAbsorption spectroscopyVibrationAtomic physicsIsotropyPhysics

摘要: Widths and shifts of the HF vibration-rotation absorption spectrum, induced by the pressure of rare gases, have been calculated using the Kolb-Griem-Baranger theory, for the pure rotation, 0–1, and 0–2 bands. Agreement between the calculated and experimental widths is good in general, but the calculated shifts, though having a qualitatively correct m-dependence for the most part, exceed the experimental values by a factor of 1· 3-2· 0. Isotropic effects are included to all orders, leading to three major consequences:(1) a …

参考文章(26)
C. F. Curtiss, J. O. Hirschfelder, R. B. Bird, Molecular theory of gases and liquids ,(1954)
Richard M. Stevens, William N. Lipscomb, Perturbed Hartree—Fock Calculations. III. Polarizability and Magnetic Properties of the HF Molecule Journal of Chemical Physics. ,vol. 41, pp. 184- 194 ,(1964) , 10.1063/1.1725621
J. Fiutak, J. Van Kranendonk, IMPACT THEORY OF RAMAN LINE BROADENING Canadian Journal of Physics. ,vol. 40, pp. 1085- 1100 ,(1962) , 10.1139/P62-117
R. P. Bell, Polarisibility and internuclear distance Transactions of The Faraday Society. ,vol. 38, pp. 422- 429 ,(1942) , 10.1039/TF9423800422
J. Fiutak, J. Van Kranendonk, THEORY OF THE IMPACT BROADENING OF RAMAN LINES DUE TO ANISOTROPIC INTERMOLECULAR FORCES Canadian Journal of Physics. ,vol. 41, pp. 21- 32 ,(1963) , 10.1139/P63-003
J. H. Jaffe, A. Rosenberg, M. A. Hirshfeld, N. M. Gailar, Pressure‐Induced Shifts of Hydrogen Fluoride Lines Due to Noble Gases The Journal of Chemical Physics. ,vol. 43, pp. 1525- 1528 ,(1965) , 10.1063/1.1696965
E. J. Stansbury, M. F. Crawford, H. L. Welsh, DETERMINATION OF RATES OF CHANGE OF POLARIZABILITY FROM RAMAN AND RAYLEIGH INTENSITIES Canadian Journal of Physics. ,vol. 31, pp. 954- 961 ,(1953) , 10.1139/P53-083
M. G. Mason, W. G. Von Holle, D. W. Robinson, Mid‐ and Far‐Infrared Spectra of HF and DF in Rare‐Gas Matrices The Journal of Chemical Physics. ,vol. 54, pp. 3491- 3499 ,(1971) , 10.1063/1.1675371