Synthesis and Characterization of Pincer-Molybdenum Precatalysts for CO2 Hydrogenation
作者： Yuanyuan Zhang , Paul G. Williard , Wesley H. Bernskoetter
DOI: 10.1021/ACS.ORGANOMET.5B00955
关键词: Chemistry 、 Medicinal chemistry 、 Pincer ligand 、 Formate 、 Substituent 、 Lewis acids and bases 、 Agostic interaction 、 Metal 、 Organic chemistry 、 Pincer movement 、 Molybdenum
摘要: … , (κ 4 -PN Me P)Mo(C 2 H 4 )(κ 2 -O 2 CH), upon exposure to CO 2 . This species serves as a promotor of CO 2 hydrogenation to formate under basic conditions, a rare transformation for …
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