Advances in metal carbene chemistry

摘要: Early Days of Transition-Metal Carbene Complexes.- Carbyne to Conversion Reactions at Hetero-Nuclear Dimetal Centres.- Stable, Terminal Methylene (=CH2) Complexes Ruthenium, Osmium and Iridium.- Metal-Mediated Cyclization Alkynes Carbenes: A New Route Toward Highly Substituted Cyclopentanoids.- N, N?,N?, N?-Functionalised Electron-Rich Alkenes Their Role in Chemistry.- Synthesis Properties Chlorotris(1,3 Dibenzylimidazolidin-2-Ylidene)Rhodium(I) Some Related Compounds.- Cyclic Acyclic Derived from Isocyanide Ligands Palladium(II) Platinum(II).- Hydridocarbene Platinum(II) Electrophilic Cleavage C-F Bonds Hydridotrifluoromethyl Compounds by Proton Acids.- Potential Metal-Carbene the Development Polymer-Supported Coordination Activation Isocyanides Metal Isonitrile Tungsten with Electrophiles.- Alkynes.- Metal-Carbon-Sulfur Ring Iron.- ?2-Carbene Cyanocarbene Dinuclear Derivatives Organometallic Synthons for Anionic Thiocarbene ?-Deprotonated Thione Opening Oxirane Oxetane Rings Conjugate Base Pentacarbonyl(Methoxy-Methyl)Chromium Complex Presence BF3.Et2O.- Formation Metal-Carbon Double R3SiX Elimination.- Ligand Migrations Coordinated Carbene.- (Butadiene)Zirconocene Structure Reactivity Vinylcarbene [W(=CPh-CH=CRMe)Br2(CO)2L] (R = H,Me L 4-Picoline). Is Vinyl Group Acting as a Pure ?-Donor Ligand?.- Dioxophosphinomethylidene Molybdenum(VI)Complexes.- Benzylidene(Pentacarbonyl) In-Situ Generation Benzylidene [Cp(CO)2W=CH(Tol)]+ Its Selective Organic Synthesis: Novel Applications Annulation Reactions.- C=C Insertion Allenes, Heterocumulenes Acid Amides Into M=C Fischer Photolytic Chromium Optically Active, Biologically Active 53Cr Nuclear Magnetic Resonance Studies Pentacarbonylchromium Synthesis, Type C5H5(CO)(L)Fe=CHR+.- The To Donor-Acceptor-Substituted Cyclopropanes.- Reaction between or Carbenes Phosphinidenes.- Alkene-Carbene Chromium: Acetylenes Induced Catalysts Olefin Metathesis.- Mo(NtBu)(=CHtBu)(CH2But)2 Alcohols: Competition Molybdenum Carbon Single Bond Reactivities.- Metathesis Polymerization Norbornene Initiated Tungsten-Carbene Complexes: Relative Stability Intermediate Tungstenacyclobutane Preparation Several Alkylidene W(CHR?)(N-2, 6-C6H3-iPr2)(OR)2 Tungstacyclobutane How Choice Controls Activity.- On Dichloro-W-Carbenes Photo-Catalytic on Stoichiometric Catalytic other Imines Complexes. Part XVI.- Polymerisation Heterogeneous Homogeneous Schrock-Type XVII.- Easily Accessible Tungsten: Application Synthesis.- Reagents Prepared Reduction Dihaloalkanes Low Valent Titanium Chromium.- Monothioacetal Determination Electron Density Distributions - Recent Experimental Results.