Nitration of Phenol over a ZSM-5 Zeolite

作者: M. Arshadi , M. Ghiaci , A. Gil

DOI: 10.1021/IE901862Q

关键词: ZeoliteInorganic chemistryNitrationCatalysisPhenolNitric acidOrganic chemistrySolventChemistrySolvent effectsSelectivity

摘要: In this paper, liquid phase nitration of phenol over a solid acid catalyst, ZSM-5 zeolite, was investigated by nitric (60%) under various solvent and temperature conditions. The performance the in ortho para positions is suggested to derive from amount catalyst effects. loading level substrate inside or outside pores zeolite makes relatively high selectivity product. However, experimental results are accounted for important role ortho/para selectivity.

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