Cu-Co bi-metal catalyst prepared by perovskite CuO/LaCoO3 used for higher alcohol synthesis from syngas

作者: Yuzhen Fang , Yuan Liu , Wei Deng , Junhai Liu

DOI: 10.1016/S2095-4956(14)60181-9

关键词: CopperChemistryInorganic chemistryDispersion (chemistry)CatalysisBimetallic stripCobaltPerovskite (structure)BimetalSyngas

摘要: Abstract Cu-Co bi-metal catalysts derived from CuO/LaCoO 3 perovskite structure were prepared by one-step citrate complexing method, and the evolution reaction to 2 C/La O CO under H pretreatment was investigated techniques of XRD, TPR TEM. The results suggest that a much higher dispersion copper significantly enhanced reduction cobalt, stronger interaction between cobalt ions in LaCoO particles led formation bi-metallic reduced enrichment Co on surface bimetallic particles. highly active selective for alcohol synthesis syngas due presence copper-modified C species.

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