作者: Tateo SUZUKI , Keiji IGARASHI , Kieko HASE , Katura TUZIMURA
关键词: Crystallography 、 Carbonyl group 、 Hydantoin 、 Circular dichroism 、 Amino acid 、 Optical rotatory dispersion 、 Chemistry 、 Stereochemistry 、 Cotton effect
摘要: Optical rotatory dispersion (ORD) and circular dichroism (CD) of 17 amino acid hydantoins were measured between 190 600 nm. Most exhibited the negative Cotton effect which showed trough 238 245 The CD was also observed 212 236 attributable to n→π* transition carbonyl group at C-4 hydantoin ring.