Matrix isolation studies of methyl cyanide and methyl isocyanide in solid argon
作者： Teresa B. Freedman , Eugene R. Nixon
DOI: 10.1016/0584-8539(72)80107-7
关键词: Matrix isolation 、 Methyl isocyanide 、 Dimer 、 Monomer 、 Cyanide 、 Argon 、 Crystallography 、 Absorption (chemistry) 、 Chemistry 、 Photochemistry 、 Molecule
摘要: Abstract The i.r. spectra of CH3CN, CD3CN, CH3NC, CD3NC and CH3N13C have been investigated in solid argon matrices at 20°K. the monomeric species indicate that matrix environment removes degeneracy E modes. Absorption features attributed to pure mixed dimer force constant calculations support an antiparallel alignment molecules which interaction is through CN or NC groups.
harvard.edu
elsevier.com
sci-hub.se 参考文章(20)
B.H. Thomas, W.J. Orville-Thomas, Molecular parameters and bond structure: Part 8. Environmental effects on v(CN) bond stretching frequencies Journal of Molecular Structure. ,vol. 3, pp. 191- 206 ,(1969) , 10.1016/0022-2860(69)87003-1
Teresa B. Freedman, Eugene R. Nixon, Infrared Matrix‐Isolation Studies of BrCN and CICN: Fermi Resonance and Dimer Structure The Journal of Chemical Physics. ,vol. 56, pp. 698- 707 ,(1972) , 10.1063/1.1677218
A. M. Saum, Intermolecular association in organic nitriles; the CN dipole-pair bond Journal of Polymer Science. ,vol. 42, pp. 57- 66 ,(1960) , 10.1002/POL.1960.1204213907
F.W. Parker, A.H. Nielsen, W.H. Fletcher, The infrared absorption spectrum of methyl cyanide vapor Journal of Molecular Spectroscopy. ,vol. 1, pp. 107- 123 ,(1957) , 10.1016/0022-2852(57)90014-0
Joshua Jortner, Stuart A. Rice, Cooperative Exciton States in Molecular Crystals Journal of Chemical Physics. ,vol. 44, pp. 3364- 3374 ,(1966) , 10.1063/1.1727239
S. N. Ghosh, Ralph Trambarulo, Walter Gordy, Electric Dipole Moments of Several Molecules from the Stark Effect The Journal of Chemical Physics. ,vol. 21, pp. 308- 310 ,(1953) , 10.1063/1.1698877
J.G. Mottern, W.H. Fletcher, The infrared spectrum of methyl-d3-isocyanide Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 18, pp. 995- 1003 ,(1962) , 10.1016/0371-1951(62)80105-2
The second virial coefficients of organic vapours Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 196, pp. 113- 125 ,(1949) , 10.1098/RSPA.1949.0018
R. L. Williams, Infrared Spectrum of Methyl Isocyanide The Journal of Chemical Physics. ,vol. 25, pp. 656- 660 ,(1956) , 10.1063/1.1743022
J.L. Duncan, The calculation of force constants and normal coordinates—V constrained force fields for a series of methyl and dimethyl compounds of 3-fold symmetry Spectrochimica Acta. ,vol. 20, pp. 1197- 1221 ,(1964) , 10.1016/0371-1951(64)80168-5