Electrochemical polymerization of a β–β linkages polythiophene derivative based on 2,5-diphenyl-thiophene
作者： Chunan Ma , Yi Xu , Cheng Zhang , Yu Xu , Wenqin Xiang
DOI: 10.1016/J.JELECHEM.2009.07.004
关键词: Polymer chemistry 、 Conductive polymer 、 Polymerization 、 Polythiophene 、 Polymer 、 Boron trifluoride 、 Thiophene 、 Cyclic voltammetry 、 Fluorescence spectrometry 、 Chemistry 、 Organic chemistry
摘要: Abstract Poly(2,5-diphenyl-thiophene) (PDPT) is polymerized electrochemically in pure boron trifluoride diethyl etherate (BFEE). FT-IR characterization approves that PDPT a β–β linkages polymer. Cyclic voltammetry (CV) tests show the as-grown polymer exhibits reversible and stable redox behaviors. Scanning electron micrographs (SEM) observation indicates morphology of film relatively smooth compact. And soluble part CHCl 3 can emit strong blue light, implying wider bandgap than polythiophene.
elsevier.com
sci-hub.se 参考文章(26)
K. Tamao, S. Kodama, I. Nakajima, M. Kumada, A. Minato, K. Suzuki, Nickel-phosphine complex-catalyzed Grignard coupling—II Tetrahedron. ,vol. 38, pp. 3347- 3354 ,(1982) , 10.1016/0040-4020(82)80117-8
Jean Roncali, Conjugated poly(thiophenes): synthesis, functionalization, and applications Chemical Reviews. ,vol. 92, pp. 711- 738 ,(1992) , 10.1021/CR00012A009
Zhipan Zhang, Gaoquan Shi, Electrochemical polymerization of 3-phenylthiophene Journal of Electroanalytical Chemistry. ,vol. 569, pp. 197- 202 ,(2004) , 10.1016/J.JELECHEM.2004.03.001
Jiaxiong Wang, Infrared spectroelectrochemical studies on deactivation of polythiophene films Electrochimica Acta. ,vol. 39, pp. 417- 429 ,(1994) , 10.1016/0013-4686(94)80081-2
Joke J. Apperloo, L. “Bert” Groenendaal, Hilde Verheyen, Manickam Jayakannan, René A. J. Janssen, Ahmed Dkhissi, David Beljonne, Roberto Lazzaroni, Jean-Luc Brédas, Optical and redox properties of a series of 3,4-ethylenedioxythiophene oligomers. Chemistry: A European Journal. ,vol. 8, pp. 2384- 2396 ,(2002) , 10.1002/1521-3765(20020517)8:10<2384::AID-CHEM2384>3.0.CO;2-L
GR Goward, F Leroux, LF Nazar, None, Poly(pyrrole) and poly(thiophene)/vanadium oxide interleaved nanocomposites: positive electrodes for lithium batteries Electrochimica Acta. ,vol. 43, pp. 1307- 1313 ,(1998) , 10.1016/S0013-4686(97)10035-4
M.R. Andersson, W. Mammo, T. Olinga, M. Svensson, M. Theander, O. Inganäs, Synthesis of regioregular phenyl substituted polythiophenes with FeCl3 Synthetic Metals. ,vol. 101, pp. 11- 12 ,(1999) , 10.1016/S0379-6779(98)00759-0
D. Tyler McQuade, Anthony E. Pullen, Timothy M. Swager, Conjugated polymer-based chemical sensors. Chemical Reviews. ,vol. 100, pp. 2537- 2574 ,(2000) , 10.1021/CR9801014
Gregory A. Sotzing, John R. Reynolds, Peter J. Steel, Electrochromic conducting polymers via electrochemical polymerization of bis(2-(3,4-ethylenedioxy)thienyl) monomers Chemistry of Materials. ,vol. 8, pp. 882- 889 ,(1996) , 10.1021/CM9504798
Edwin WH Jager, Elisabeth Smela, Olle Inganas, Microfabricating Conjugated Polymer Actuators Science. ,vol. 290, pp. 1540- 1545 ,(2000) , 10.1126/SCIENCE.290.5496.1540