Composition and Properties of Hot‐Pressed SiC‐AIN Solid Solutions

作者: ROBERT RUH , AVIGDOR ZANGVIL

DOI: 10.1111/J.1151-2916.1982.TB10429.X

关键词: Materials scienceFlexural strengthSolid solutionMineralogyIndentation hardnessComposite materialGrain sizeAtmospheric temperature range

摘要: High-density SiC-AIN compositions were fabricated from powder mixtures by hot-pressing in the 1700° to 2300°C temperature range. At 2100°C, a 2H solid solution was found =35 100 wt% AlN. The single-phase samples had steep composition gradients of >10%/μm within grains. Lattice parameters closely followed Vegard's law. For with <35% AIN, multiphase assemblages found. Increasing grain size observed for increasing firing SiC and AIN. Grain solutions significantly smaller than or AIN fired same temperature. Microhardness values decreased linearly region content. Flexural strengths size. SiC, low materials hot-pressed at 2100°C.

参考文章(9)
SVANTE PROCHAZKA, RONALD M. SCANLAN, Effect of Boron and Carbon on Sintering of SIC Journal of the American Ceramic Society. ,vol. 58, pp. 72- 72 ,(1975) , 10.1111/J.1151-2916.1975.TB18990.X
I. B. CUTLER, P. D. MILLER, W. RAFANIELLO, H. K. PARK, D. P. THOMPSON, K. H. JACK, New materials in the Si–C–Al–O–N and related systems Nature. ,vol. 275, pp. 434- 435 ,(1978) , 10.1038/275434A0
N J Zaluzec, H L Fraser, A modified specimen stage for X-ray analysis in a TEM Journal of Physics E: Scientific Instruments. ,vol. 9, pp. 1051- 1052 ,(1976) , 10.1088/0022-3735/9/12/009
Jean-Marie Bind, Phase transformation during hot-pressing of cubic SiC Materials Research Bulletin. ,vol. 13, pp. 91- 96 ,(1978) , 10.1016/0025-5408(78)90071-5
P. Krishna, R.C. Marshall, The structure, perfection and annealing behaviour of SiC needles grown by a VLS mechanism Journal of Crystal Growth. ,vol. 9, pp. 319- 325 ,(1971) , 10.1016/0022-0248(71)90249-1
P. Krishna, R.C. Marshall, Direct transformation from the 2H to the 6H structure in single-crystal silicon carbide Journal of Crystal Growth. ,vol. 11, pp. 147- 150 ,(1971) , 10.1016/0022-0248(71)90178-3
P. T. B. Shaffer, A review of the structure of silicon carbide Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 25, pp. 477- 488 ,(1969) , 10.1107/S0567740869002457
JAMES W. McCAULEY, N. D. CORBIN, Phase Relations and Reaction Sintering of Transparent Cubic Aluminum Oxynitride Spinel (ALON) Journal of the American Ceramic Society. ,vol. 62, pp. 476- 479 ,(1979) , 10.1111/J.1151-2916.1979.TB19109.X
TOKUHEI TAGAI, SHIGEHO SUENO, RYOICHI SADANAGA, THERMAL TRANSFORMATIONS IN SiC CRYSTALS Mineralogical Journal. ,vol. 6, pp. 240- 248 ,(1971) , 10.2465/MINERJ1953.6.240