Raman study of molecular dynamics of inorganic fluoroxidizers in nonaqueous solvents—Part 2. Xenon difluoride in hydrogen fluoride and bromine pentafluoride
作者： Sh.Sh. Nabiev , I.I. Ostroukhova
DOI: 10.1016/0584-8539(93)80058-I
关键词: Chemistry 、 Inorganic compound 、 Analytical chemistry 、 Bromine pentafluoride 、 Xenon 、 Raman spectroscopy 、 Hydrogen fluoride 、 Stereochemistry 、 Vibrational energy relaxation 、 Triatomic molecule 、 Xenon difluoride
摘要: Abstract The Raman spectra of the totally symmetric ν 1 (Σ + g ) mode xenon dilluoride molecules have been measured in HF and BrF 5 solutions at various concentrations. It is shown that XeF 2 spectrum has a complicated structure with three visible peaks. contour was resolved on elementary components which were identified. vibrational rotational correlation functions as well characteristics times calculated. concluded band width to be attributed dephasing, whereas contribution from relaxation found less importance.
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