Influence of Plasticizer on a PEO based K + ion conducting Polymer electrolyte system for Battery applications
作者： N. Krishna Jyothi , G. Sunita Sundari , K. Vijaya Kumar
DOI:
关键词: Short circuit 、 Conductive polymer 、 Electrochemical cell 、 Battery (electricity) 、 Polymer 、 Materials science 、 Electrolyte 、 Open-circuit voltage 、 Conductivity 、 Polymer chemistry 、 Chemical engineering
摘要: Poly Ethylene Oxide (PEO) based Solid polymer electrolyte films with KHCO3 and KHCO3+ plasticizer (Dimethyl formamide) have been prepared using a solution casting technique. The complexation of the Polymer PEO DMF was confirmed by IR XRD studies. conductivity-temperature plots showed an increase in conductivity increasing temperature. is about ten times larger plasticized (PEO + KHCO3) systems compared pure system. transference data indicated that charge transport these predominantly due to ions. Using this system, battery or electrochemical cell configuration K / plasticizer) (I2 C Electrolyte) fabricated its discharge characteristics were studied for constant load 100 KΩ. Open circuit voltage (OCV), Short current (SCC), Discharge time, Current density Power evaluated. A number other parameters associated evaluated from earlier reported paper. Keywords:Solid electrolyte, Solution technique, Transport number, characteristics.
sphinxsai.com 参考文章(15)
M. Jaipal Reddy, T. Sreekanth, M. Chandrashekar, U. V. Subba Rao, Ion transport and electrochemical cell characteristic studies of a new (PVP 1 NaNO3) polymer electrolyte system Journal of Materials Science. ,vol. 35, pp. 2841- 2845 ,(2000) , 10.1023/A:1004707521250
Fast Ion Transport in Solids Springer Netherlands. ,(1993) , 10.1007/978-94-011-1916-0
P.S. Anantha, K. Hariharan, Structure and ionic transport studies of sodium borophosphate glassy system Materials Chemistry and Physics. ,vol. 89, pp. 428- 437 ,(2005) , 10.1016/J.MATCHEMPHYS.2004.09.029
J. Siva Kumar, M. Jaipal Reddy, U. V. Subba Rao, Ion transport and battery studies of a new (PVP+KIO3) polymer electrolyte system Journal of Materials Science. ,vol. 41, pp. 6171- 6173 ,(2006) , 10.1007/S10853-006-0162-0
E. Laxmi Narsaiah, M. Jaipal Reddy, U.V. Subba Rao, Study of a new polymer electrolyte (PVP + KYF4) for solid-state electrochemical cells Journal of Power Sources. ,vol. 55, pp. 255- 257 ,(1995) , 10.1016/0378-7753(95)02198-P
R C Agrawal, G P Pandey, Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview Journal of Physics D. ,vol. 41, pp. 223001- ,(2008) , 10.1088/0022-3727/41/22/223001
J Siva Kumar, K Vijaya Kumar, AR Subrahmanyam, M Jaipal Reddy, None, Conductivity study of polyethylene oxide (PEO) complexed with sodium bicarbonate Journal of Materials Science. ,vol. 42, pp. 5752- 5755 ,(2007) , 10.1007/S10853-006-0743-Y
S Sreepathi Rao, KV Satyanarayana Rao, Md Shareefuddin, UV Subba Rao, Suresh Chandra, None, Ionic conductivity and battery characteristic studies on PEO+AgNO3 polymer electrolyte Solid State Ionics. ,vol. 67, pp. 331- 334 ,(1994) , 10.1016/0167-2738(94)90026-4
T Sreekanth, M Jaipal Reddy, U.V Subba Rao, Polymer electrolyte system based on (PEO+KBrO3) — its application as an electrochemical cell Journal of Power Sources. ,vol. 93, pp. 268- 272 ,(2001) , 10.1016/S0378-7753(00)00558-9
J. Bruce Wagner, Carl Wagner, Electrical Conductivity Measurements on Cuprous Halides The Journal of Chemical Physics. ,vol. 26, pp. 1597- 1601 ,(1957) , 10.1063/1.1743590