Electrochemical properties of gas-generated silver nanoparticles in the presence of cyano- and chloride-containing compounds.
作者： Armando J. Marenco , David B. Pedersen , Shiliang Wang , Michael W. P. Petryk , Heinz-Bernhard Kraatz
DOI: 10.1039/B909748A
关键词: Inorganic chemistry 、 Nanoparticle 、 Sulfide 、 Supporting electrolyte 、 Sulfur 、 Silver nanoparticle 、 Chloride 、 Oxide 、 Chemistry 、 Electrochemistry
摘要: The electrochemistry of gas-generated naked Ag nanoparticles deposited on indium-tin oxide covered glass plates is compared to bulk polycrystalline Ag. nano-specific has been identified and includes the preferential formation β-oxides. In 100 mM KOH supporting electrolyte, disruption β-oxide exploited test for presence diethyl cyanophosphonate. While in 8.0 M KOH, enhanced leading testing capabilities 2-chloroethyl ethyl sulfide. These non-redox active compounds are effective simulants chemical warfare agents Tabun nerve agent sulfur mustard, respectively.
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