Hydrogenation of Organic Compounds with Synthesis Gas

摘要: Publisher Summary This chapter describes the homogeneous character of hydrogenation unsaturated compounds with synthesis gas and a cobalt catalyst, organic compounds, properties, structure, preparation dicobalt octacarbonyl hydrocarbonyl, mechanism hydrogenation. One most intriguing features catalytic is effect poisons. Poisoning usually results from interference one or all first four requirements stated above—that is, poison in some manner preferentially adsorbed by catalyst thus, inhibits retards desired The activity usual metallic catalysts (nickel, cobalt, palladium, platinum) for ethylenic substances impaired carbon monoxide. Carbon monoxide has also shown to inhibit copper catalyst. reaction that probably hydrocarbonyl.