Hydrodeoxygenation of phenol on bifunctional Ni-based catalysts: Effects of Mo promotion and support

作者: E. Kordouli , B. Pawelec , C. Kordulis , A. Lycourghiotis , J.L.G. Fierro

DOI: 10.1016/J.APCATB.2018.07.012

关键词: DecalinNuclear chemistryCatalysisSulfidationAdsorptionAmorphous silica-aluminaContext (language use)ChemistryBifunctionalHydrodeoxygenation

摘要: Hydrodeoxygenation (HDO) of phenol dissolved in decalin was studied over H 2-activated Ni and Mo-Ni catalysts supported on alumina and amorphous silica alumina (ASA) in the context of the O-removal from bio-liquids. The activity test was carried out in a flow reactor at 310° C and total hydrogen pressure of 3 MPa. The catalyst samples were characterized by several physico-chemical techniques (S BET, H 2-TPR, HRTEM, DRIFT spectroscopy of adsorbed CO and NH 3, Raman spectroscopy, XPS, SEM-EDS and HRTEM) in order to …

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