Selective isomerization of epoxides to allylic alcohols catalyzed by TiO2-supported gold nanoparticles.
作者： Christos Raptis , Hermenegildo Garcia , Manolis Stratakis
关键词: Selectivity 、 Isomerization 、 Combinatorial chemistry 、 Catalysis 、 Reaction mechanism 、 Chemistry 、 Epoxide 、 Concerted reaction 、 Heterogeneous catalysis 、 Photochemistry 、 Allylic rearrangement
摘要: ReacTiO(2)ns for rings: Gold nanoparticles supported on TiO(2) are used as a novel heterogeneous catalyst the isomerization of epoxides to allylic alcohols by concerted mechanism (see scheme). The reaction proceeds in high yields and product selectivity is often remarkable.
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