Structural and magnetic properties of ZnFe 2 O 4 films deposited by low sputtering power

作者: Jin-long Li , Zhong Yu , Ke Sun , Xiao-na Jiang , Zhong-wen Lan

DOI: 10.1007/S12613-012-0655-6

关键词: Thin filmNuclear magnetic resonanceAnalytical chemistrySputter depositionAntiferromagnetismSpinelMaterials scienceMagnetizationSurface energySputteringFerromagnetism

摘要: To validate the correctness of Hartman-Perdok Theory (HPT), which indicates that {111} planes have lowest surface energy in spinel ferrites, plane orientated ZnFe2O4 thin films on Si(100), Si(111), and SiO2(500 nm)/Si(111) substrates were obtained through a radio frequency (RF) magnetron sputtering method with low power 80 W. All experiments prove atom determined by plays an important role growth films, it matches well HPT. The exhibit ferromagnetism magnetization 84.25 kJ/mol at room temperature, is different from bulk counterpart (antiferromagnetic as usual). can be used high-quality oriented inducing buffer layers for other (Ni, Mn)Zn ferrite may high potential magnetic films-based devices.

参考文章(23)
P. Hartman, Crystal growth : an introduction North-Holland Pub. Co. , American Elsevier. ,(1973)
P. M. G. Nambissan, C. Upadhyay, H. C. Verma, Positron lifetime spectroscopic studies of nanocrystalline ZnFe2O4 Journal of Applied Physics. ,vol. 93, pp. 6320- 6326 ,(2003) , 10.1063/1.1569973
Hans J. Herrmann, Growth: An Introduction ogff. ,vol. 100, pp. 3- 20 ,(1986) , 10.1007/978-94-009-5165-5_1
W. D. Davis, T. A. Vanderslice, Ion Energies at the Cathode of a Glow Discharge Physical Review. ,vol. 131, pp. 219- 228 ,(1963) , 10.1103/PHYSREV.131.219
C.F. Woensdregt, Computation of surface energies in an electrostatic point charge model. I : Theory Physics and Chemistry of Minerals. ,vol. 19, pp. 52- 58 ,(1992) , 10.1007/BF00206800
Naoki Wakiya, Kazuo Shinozaki, Nobuyasu Mizutani, Stress-induced magnetization for epitaxial spinel ferrite filmsthrough interface engineering Applied Physics Letters. ,vol. 85, pp. 1199- 1201 ,(2004) , 10.1063/1.1780603
N.E. Kazantseva, Yu.I. Bespyatykh, I. Sapurina, J. Stejskal, J. Vilčáková, P. Sáha, Magnetic materials based on manganese zinc ferrite with surface-organized polyaniline coating Journal of Magnetism and Magnetic Materials. ,vol. 301, pp. 155- 165 ,(2006) , 10.1016/J.JMMM.2005.06.015
Che-Ming Liu, Jyh-Chen Chen, Growth of Mg–Al spinel microcrystals on a sapphire surface using a solution-precipitation method Applied Physics Letters. ,vol. 89, pp. 011912- ,(2006) , 10.1063/1.2220062
R. Dekkers, C.F. Woensdregt, P. Wollants, Surface modelling of crystalline non-metallic inclusions Journal of Non-crystalline Solids. ,vol. 282, pp. 49- 60 ,(2001) , 10.1016/S0022-3093(01)00328-3