Radiation grafting of styrene and acrylonitrile to cellulose and polyethylene

作者: S Hassanpour

DOI: 10.1016/S0969-806X(98)00310-7

关键词: Polymer chemistryPolyethyleneMaterials scienceComonomerPolymerizationStyreneGraftingLow-density polyethyleneCopolymerAcrylonitrile

摘要: Abstract Radiation induced graft polymerization is one of the best methods for obtaining material with new properties. In this work, radiation grafting styrene, mixture styrene and acrylonitrile to cellulose polyethylene in presence methanol as a solvent by mutual method discussed. At low dose rate, high yields were obtained from two systems used, due lesser termination free radicals polymer growing recombination primary radicals, resulting longer chain length grafted copolymer. system acrylonitrile, comonomer technique was used controlled homopolymer formation during polymerization. Water uptake decreased increasing yields. Grafted can be molded some extent percent grafting, transparent obtained. By styrene–acrylonitrile density degree crosslinking observed.

参考文章(9)
Arthur Charlesby, Atomic radiation and polymers Pergamon Press. ,(1960)
Ali Hebeish, James Thomas Guthrie, The chemistry and technology of cellulosic copolymers ,(1981)
Paul A. Dworjanyn, John L. Garnett, The role of multifunctional acrylates in radiation grafting and curing reactions International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry. ,vol. 33, pp. 429- 436 ,(1989) , 10.1016/1359-0197(89)90107-0
Chye H. Ang, John L. Garnett, Mervyn A. Long, Ronald Levot, Novel additives for accelerating radiation grafting of monomers to polymers in acid media. Radiation Physics and Chemistry. ,vol. 22, pp. 831- 839 ,(1983) , 10.1016/0146-5724(83)90102-4
Chye H. Ang, Neil P. Davis, John L. Garnett, Nguyen T. Yen, The nature of bonding during film formation of polyolefins and cellulose using UV and ionizing radiation initiation Radiation Physics and Chemistry (1977). ,vol. 9, pp. 831- 841 ,(1977) , 10.1016/0146-5724(77)90194-7
Walter J. Chappas, Joseph Silverman, The effect of acid on the radiation-induced grafting of styrene to polyethylene Radiation Physics and Chemistry (1977). ,vol. 14, pp. 847- 852 ,(1979) , 10.1016/0146-5724(79)90120-1
Visay Viengkhou, Loo-Teck Ng, John L. Garnett, The effect of additives on the enhancement of methyl methacrylate grafting to cellulose in the presence of UV and ionising radiation Radiation Physics and Chemistry. ,vol. 49, pp. 595- 602 ,(1997) , 10.1016/S0969-806X(97)00001-7