Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates
作者： N MIZUNO , K YAMAGUCHI , K KAMATA
DOI: 10.1016/J.CCR.2004.11.019
关键词: Derivative (chemistry) 、 Catalysis 、 Hydrogen peroxide 、 Organic chemistry 、 Chemistry 、 Protonation 、 Salt (chemistry) 、 Olefin fiber
摘要: … First, we examined the epoxidation of 1-octene with hydrogen peroxide catalyzed by a series of silicotungstates in acetonitrile at 305 K. The silicotungstates, [α-SiW 9 O 34 ] 10− , [γ-SiW …
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