Investigation of different column configurations for the ethyl acetate synthesis via reactive distillation
作者： Markus Klöker , EY Kenig , Andrzej Górak , AP Markusse , Gerard Kwant
DOI: 10.1016/S0255-2701(03)00084-9
关键词: Catalysis 、 Reactive distillation 、 Ethyl acetate synthesis 、 Analytical chemistry 、 Column (database) 、 Laboratory scale 、 Scale (ratio) 、 SCALE-UP 、 Chromatography 、 Chemistry
摘要: Abstract The ethyl acetate synthesis via reactive distillation is studied theoretically and experimentally using different catalytic packings. Experiments are carried out at laboratory scale in a 50 mm diameter column with packing height of 3 m, semi-industrial 162 12 m. experimental set-up similar for both cases. commercially available packings KATAPAK®-S two variants MULTIPAK®. Modelling performed rate-based stage model. simulation environment ASPEN Custom Modeler™ used the implementation solution model equations. results simulations agree well corresponding results. In addition, suitable operating conditions influence selected internal on conversion product purity investigated. developed enables scale-up from to industrial size columns, based respective characteristics.
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sci-hub.se 参考文章(21)
Robert J. Carland, Fractionation tray for catalytic distillation ,(1992)
Ulrich Kunz, Ulrich Hoffman, Preparation of catalytic polymer/ceramic ionexchange packings for reactive distillation columns Studies in Surface Science and Catalysis. ,vol. 91, pp. 299- 308 ,(1995) , 10.1016/S0167-2991(06)81766-0
Ross Taylor, R. Krishna, Multicomponent mass transfer ,(1993)
V. H Agreda, W. H Heise, High-purity methyl acetate via reactive distillation Chemical Engineering Progress. ,vol. 86, pp. 40- 46 ,(1990)
C. F. Curtiss, J. O. Hirschfelder, R. B. Bird, Molecular theory of gases and liquids ,(1954)
Wugeng Liang, Zhanwen Wang, Yong Jin, Zhiqing Yu, Sheng Yang, Performance of a three-phase fluidized bed as a reactive distillation device Chemical Engineering & Technology. ,vol. 19, pp. 456- 461 ,(1996) , 10.1002/CEAT.270190512
EY Kenig, H Bäder, A Górak, B Beßling, T Adrian, H Schoenmakers, None, Investigation of ethyl acetate reactive distillation process Chemical Engineering Science. ,vol. 56, pp. 6185- 6193 ,(2001) , 10.1016/S0009-2509(01)00206-8
J.M van Baten, J Ellenberger, R Krishna, Hydrodynamics of reactive distillation tray column with catalyst containing envelopes: experiments vs. CFD simulations Catalysis Today. ,vol. 66, pp. 233- 240 ,(2001) , 10.1016/S0920-5861(00)00625-8
Jiřı́ Hanika, Quido Smejkal, Jiřı́ Kolena, 2-Methylpropylacetate synthesis via catalytic distillation Catalysis Today. ,vol. 66, pp. 219- 223 ,(2001) , 10.1016/S0920-5861(00)00652-0
P.J.M. Lebens, F. Kapteijn, S.T. Sie, J.A. Moulijn, Potentials of internally finned monoliths as a packing for multifunctional reactors Chemical Engineering Science. ,vol. 54, pp. 1359- 1365 ,(1999) , 10.1016/S0009-2509(99)00060-3