Mesoporous magnetic g-C3N4 nanocomposites for photocatalytic environmental remediation under visible light.

作者: Junhong Wang , Xianzhao Shao , Junhai Liu , Qiang Zhang , Xiaohui Ji

DOI: 10.1016/J.ECOENV.2020.111147

关键词: PhotocatalysisSaturation (magnetic)MagnetismMesoporous materialVisible spectrumNanomaterialsMaterials scienceNanocompositeRhodamine BChemical engineering

摘要: Abstract Mesoporous magnetic Fe3O4/g-C3N4 nanocomposites were synthesized by a facile precipitation method using deionized water as solution. And the prepared materials characterized mean of various detection methods. At same time, photocatalytic activity synthetic material photocatalyst under visible light was tested taking degradation rhodamine B in mark. Results show that as-synthesized have high specific surface areas about 5–10.5 times pure g-C3N4 and saturation magnetizations, which can ensure smooth recovery used nanomaterials action external field. The addition Fe3O4 greatly extents response range to reduces recombination rate photoinduced electron-hole pairs. Meanwhile, increases so ratio reached 97.6% after 4 h irradiation. Furthermore, also excellent stability almost not reduce 5 continuous reuse photocatalyst. Free radical scavenging experiments shows hydroxyl groups are main free radicals reaction, peroxyradicals holes play secondary role. Therefore, it be predicted mesoporous will broad application prospect environmental remediation.

参考文章(61)
Huogen Yu, Fengyun Chen, Feng Chen, Xuefei Wang, In situ self-transformation synthesis of g-C3N4-modified CdS heterostructure with enhanced photocatalytic activity Applied Surface Science. ,vol. 358, pp. 385- 392 ,(2015) , 10.1016/J.APSUSC.2015.06.074
Dandan Zheng, Chenyang Pang, Yuxing Liu, Xinchen Wang, Shell-engineering of hollow g-C3N4 nanospheres via copolymerization for photocatalytic hydrogen evolution Chemical Communications. ,vol. 51, pp. 9706- 9709 ,(2015) , 10.1039/C5CC03143E
C. G. Liu, X. T. Wu, X. F. Li, X. G. Zhang, Synthesis of graphene-like g-C3N4/Fe3O4 nanocomposites with high photocatalytic activity and applications in drug delivery RSC Advances. ,vol. 4, pp. 62492- 62498 ,(2014) , 10.1039/C4RA10616D
Jie Fu, Binbin Chang, Yanlong Tian, Fengna Xi, Xiaoping Dong, Novel C3N4–CdS composite photocatalysts with organic–inorganic heterojunctions: in situ synthesis, exceptional activity, high stability and photocatalytic mechanism Journal of Materials Chemistry. ,vol. 1, pp. 3083- 3090 ,(2013) , 10.1039/C2TA00672C
C. Hinnen, D. Imbert, J.M. Siffre, P. Marcus, An in situ XPS study of sputter-deposited aluminium thin films on graphite Applied Surface Science. ,vol. 78, pp. 219- 231 ,(1994) , 10.1016/0169-4332(94)90009-4
Andrej Furlan, Ulf Jansson, Jun Lu, Lars Hultman, Martin Magnuson, Structure and bonding in amorphous iron carbide thin films. Journal of Physics: Condensed Matter. ,vol. 27, pp. 045002- ,(2015) , 10.1088/0953-8984/27/4/045002
Lei Shi, Lin Liang, Jun Ma, Fangxiao Wang, Jianmin Sun, Remarkably enhanced photocatalytic activity of ordered mesoporous carbon/g-C₃N₄ composite photocatalysts under visible light. Dalton Transactions. ,vol. 43, pp. 7236- 7244 ,(2014) , 10.1039/C4DT00087K
Yao Zheng, Jian Liu, Ji Liang, Mietek Jaroniec, Shi Zhang Qiao, Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis Energy and Environmental Science. ,vol. 5, pp. 6717- 6731 ,(2012) , 10.1039/C2EE03479D
Liying Huang, Hui Xu, Yeping Li, Huaming Li, Xiaonong Cheng, Jixiang Xia, Yuanguo Xu, Guobin Cai, Visible-light-induced WO3/g-C3N4 composites with enhanced photocatalytic activity Dalton Transactions. ,vol. 42, pp. 8606- 8616 ,(2013) , 10.1039/C3DT00115F
Xiaojuan Bai, Li Wang, Yajun Wang, Wenqing Yao, Yongfa Zhu, Enhanced oxidation ability of g-C3N4 photocatalyst via C60 modification Applied Catalysis B-environmental. ,vol. 152, pp. 262- 270 ,(2014) , 10.1016/J.APCATB.2014.01.046