Evaluation of two different scrap tires as hydrocarbon source by pyrolysis
作者： Suat Ucar , Selhan Karagoz , Ahmet R. Ozkan , Jale Yanik
DOI: 10.1016/J.FUEL.2005.04.002
关键词: Diesel fuel 、 Hydrocarbon 、 Activated carbon 、 Materials science 、 Chemical engineering 、 Pyrolytic carbon 、 Distillation 、 Carbon black 、 Pyrolysis 、 Naphtha
摘要: Abstract The main objective of the present study is to investigate effect polymer types in scrap tires on pyrolysis products. Two different (passenger car tire, PCT and truck TT) have been pyrolyzed a fixed bed reactor at temperatures 550, 650 800 °C under N 2 atmosphere. Pyrolysis products (gas, oil carbon black) obtained from TT were investigated comparatively. gaseous analyzed by GC–TCD. psychical chemical properties pyrolytic oils characterized means GC–FID, GC–MS, 1 H NMR. In addition, boiling point distributions hydrocarbons determined using simulated distillation curves comparison with commercial diesel fuel. production activated blacks (CBp) was also carried out. composition similar they contained mainly (C –C 4 ). Pyrolytic found lighter than but heavier naphtha. physical same temperature. However, aromatic sulphur content higher that TT. Furthermore, derived black more suitable for due its low ash content.
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sci-hub.se 参考文章(30)
Christopher MB Lehmann, Massoud Rostam-Abadi, Mark J Rood, Jian Sun, None, Reprocessing and reuse of waste tire rubber to solve air-quality related problems Energy & Fuels. ,vol. 12, pp. 1095- 1099 ,(1998) , 10.1021/EF9801120
M.F Laresgoiti, B.M Caballero, I de Marco, A Torres, M.A Cabrero, M.J Chomón, Characterization of the liquid products obtained in tyre pyrolysis Journal of Analytical and Applied Pyrolysis. ,vol. 71, pp. 917- 934 ,(2004) , 10.1016/J.JAAP.2003.12.003
D. Cazorla-Amorós, D. Ribes-Pérez, M.C. Román-Martínez, A. Linares-Solano, Selective porosity development by calcium-catalyzed carbon gasification Carbon. ,vol. 34, pp. 869- 878 ,(1996) , 10.1016/0008-6223(96)00026-7
Juan F González, José M Encinar, José L Canito, Juan J Rodrı́guez, Pyrolysis of automobile tyre waste. Influence of operating variables and kinetics study Journal of Analytical and Applied Pyrolysis. ,vol. 58, pp. 667- 683 ,(2001) , 10.1016/S0165-2370(00)00201-1
Mark E. Myers, Janis. Stollsteimer, Andrew M. Wims, Determination of hydrocarbon-type distribution and hydrogen/carbon ratio of gasolines by nuclear magnetic resonance spectrometry Analytical Chemistry. ,vol. 47, pp. 2010- 2015 ,(1975) , 10.1021/AC60362A020
C Roy, A Chaala, H Darmstadt, The vacuum pyrolysis of used tires Journal of Analytical and Applied Pyrolysis. ,vol. 51, pp. 201- 221 ,(1999) , 10.1016/S0165-2370(99)00017-0
Paul T. Williams, David T. Taylor, Aromatization of tyre pyrolysis oil to yield polycyclic aromatic hydrocarbons Fuel. ,vol. 72, pp. 1469- 1474 ,(1993) , 10.1016/0016-2361(93)90002-J
M. Day, J.D. Cooney, Z. Shen, Pyrolysis of automobile shredder residue: an analysis of the products of a commercial screw kiln process Journal of Analytical and Applied Pyrolysis. ,vol. 37, pp. 49- 67 ,(1996) , 10.1016/0165-2370(96)00938-2
M. Day, Z. Shen, J.D. Cooney, Pyrolysis of auto shredder residue: experiments with a laboratory screw kiln reactor ☆ Journal of Analytical and Applied Pyrolysis. ,vol. 51, pp. 181- 200 ,(1999) , 10.1016/S0165-2370(99)00016-9
A. Napoli, Y. Soudais, D. Lecomte, S. Castillo, Scrap tyre pyrolysis: Are the effluents valuable products? Journal of Analytical and Applied Pyrolysis. ,vol. 40-41, pp. 373- 382 ,(1997) , 10.1016/S0165-2370(97)00011-9