THE ELECTROCATALYTIC CHEMISTRY OF TRANSITION METAL COMPLEXES I. DEHYDROGENATION OF CYCLOHEXENE BY THE ELECTROREDUCED METAL COMPLEXES OF α,β,γ,δ-TETRAPHENYLPORPHINE I.
作者： Hironori Kageyama , Masanobu Hidai , Yasuzo Uchida
DOI: 10.1246/CL.1972.139
关键词: Benzene 、 Polymer chemistry 、 Chemistry 、 Electrolysis 、 Dehydrogenation 、 Photochemistry 、 Cyclohexene 、 Catalysis 、 Metal 、 Transition metal 、 Cobalt
摘要: The cobalt complex of α,β,γ,δ-tetraphenylporphine reduced by electrolysis had the catalytic activity dehydrogenating cyclohexene to 1,5- and 1,4-cyclohexadiene benzene. composition dehydrogenated products depended upon solvents used. An anion radical Co(I) was assumed intermediate based on e.s.r. polarographic data.
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