Microcrystalline composite particles of carbon nanotubes and calcium carbonate.

作者: William E. Ford , Akio Yasuda , Jurina M. Wessels

DOI: 10.1021/LA7026797

关键词: CrystallizationCarbon nanotubeParticlePrecipitation (chemistry)CoprecipitationChemical engineeringCalcium carbonateCalciteInorganic chemistryMaterials scienceMicrocrystalline

摘要: Coprecipitation of urea-melt modified carbon nanotubes and calcium carbonate from an aqueous solution by two methods yielded microcrystalline composite particles. Powders obtained colloidal crystallization a supersaturated that were isolated dried soon after precipitation mixture raspberry-shaped rhombohedral These shown infrared X-ray diffraction analyses to be mainly calcite. Particles kept wet for 1 day or longer before being typically entirely with edge lengths in the range 5−30 μm. Scanning electron microscopy investigations revealed adsorbed on particle surface also incorporated into interior matrix. Removal component treating particles acid nanotube shells whose size shape reflected those original

参考文章(35)
Lara A. Estroff, Lia Addadi, Steve Weiner, Andrew D. Hamilton, An organic hydrogel as a matrix for the growth of calcite crystals Organic and Biomolecular Chemistry. ,vol. 2, pp. 137- 141 ,(2004) , 10.1039/B309731E
Damir Kralj, Ljerka Brečević, Jasminka Kontrec, Vaterite growth and dissolution in aqueous solution III. Kinetics of transformation Journal of Crystal Growth. ,vol. 177, pp. 248- 257 ,(1997) , 10.1016/S0022-0248(96)01128-1
Dimitrios Tasis, Stergios Pispas, Costas Galiotis, Nikolaos Bouropoulos, Growth of calcium carbonate on non-covalently modified carbon nanotubes Materials Letters. ,vol. 61, pp. 5044- 5046 ,(2007) , 10.1016/J.MATLET.2007.03.101
I. Firkowska, M. Olek, N. Pazos-Peréz, J. Rojas-Chapana, M. Giersig, Highly ordered MWNT-based matrixes: topography at the nanoscale conceived for tissue engineering. Langmuir. ,vol. 22, pp. 5427- 5434 ,(2006) , 10.1021/LA053067E
Mitsutaka Kitamura, Crystallization and Transformation Mechanism of Calcium Carbonate Polymorphs and the Effect of Magnesium Ion. Journal of Colloid and Interface Science. ,vol. 236, pp. 318- 327 ,(2001) , 10.1006/JCIS.2000.7398
Dmitry V. Volodkin, Natalia I. Larionova, Gleb B. Sukhorukov, Protein encapsulation via porous CaCO3 microparticles templating. Biomacromolecules. ,vol. 5, pp. 1962- 1972 ,(2004) , 10.1021/BM049669E
Santosh Aryal, KC Remant Bahadur, N Dharmaraj, Kawn-Woo Kim, Hak Yong Kim, None, Synthesis and characterization of hydroxyapatite using carbon nanotubes as a nano-matrix Scripta Materialia. ,vol. 54, pp. 131- 135 ,(2006) , 10.1016/J.SCRIPTAMAT.2005.09.050
D. Tasis, D. Kastanis, C. Galiotis, N. Bouropoulos, Growth of calcium phosphate mineral on carbon nanotube buckypapers Physica Status Solidi B-basic Solid State Physics. ,vol. 243, pp. 3230- 3233 ,(2006) , 10.1002/PSSB.200669122
Wei WANG, Mamoru OMORI, Fumio WATARI, Atsuro YOKOYAMA, Novel Bulk Carbon Nanotube Materials for Implant by Spark Plasma Sintering Dental Materials Journal. ,vol. 24, pp. 478- 486 ,(2005) , 10.4012/DMJ.24.478
Uta Magdans, Xavier Torrelles, Klaus Angermund, Hermann Gies, Jordi Rius, Crystalline order of a water/glycine film coadsorbed on the (104) calcite surface. Langmuir. ,vol. 23, pp. 4999- 5004 ,(2007) , 10.1021/LA0636659