Preparation and Catalytic Properties of Single-Phase Ni–Sn Intermetallic Compound Particles by CVD of Sn(CH3)4 onto Ni/Silica

作者: Ayumu Onda , Takayuki Komatsu , Tatsuaki Yashima

DOI: 10.1006/JCAT.2001.3231

关键词: Chemical engineeringStoichiometryTemperature-programmed reductionCatalysisDehydrogenationHeterogeneous catalysisAtomic ratioInorganic chemistryTransition metalChemistryIntermetallic

摘要: … Ni–Sn IMC/SiO2 was used as a catalyst for the dehydrogenation of cyclohexane. The catalytic activity of each Ni–Sn IMC/SiO2 was much higher … than that of the Ni/SiO2 catalyst. The …

参考文章(29)
G. C. Bond, Catalysis By Metals ,(1962)
Thaddeus B Massalski, Hiroaki Okamoto, PRnbsp Subramanian, Linda Kacprzak, William W Scott, None, Binary alloy phase diagrams ASM International. ,vol. 3, pp. 2874- ,(1986)
M.T. Paffett, S.C. Gebhard, R.G. Windham, B.E. Koel, Chemisorption of ethylene on ordered Sn/Pt(111) surface alloys Surface Science. ,vol. 223, pp. 449- 464 ,(1989) , 10.1016/0039-6028(89)90673-0
M MASAI, Dehydrogenation activity of nickel-tin-silica catalyst Journal of Catalysis. ,vol. 38, pp. 128- 134 ,(1975) , 10.1016/0021-9517(75)90070-6
K. Soga, H. Imamura, S. Ikeda, Hydrogenation of ethylene over lanthanum-nickel (LaNi5) alloy The Journal of Physical Chemistry. ,vol. 81, pp. 1762- 1766 ,(1977) , 10.1021/J100533A010
C. Nedez, A. Theolier, F. Lefebvre, A. Choplin, J. M. Basset, J. F. Joly, Surface organometallic chemistry of tin: reactivity of tetraalkyltin complexes and tributyltin hydride toward silica Journal of the American Chemical Society. ,vol. 115, pp. 722- 729 ,(1993) , 10.1021/JA00055A049
S. H. Overbury, Yi-sha Ku, Formation of stable, two-dimensional alloy-surface phases: Sn on Cu(111), Ni(111), and Pt(111) Physical Review B. ,vol. 46, pp. 7868- 7872 ,(1992) , 10.1103/PHYSREVB.46.7868
K. Tomishige, K. Asakura, Y. Iwasawa, Design and Characterization by EXAFS, FTIR, and TEM of Rh-Sn/SiO2 Catalysts Active for NO-H2 Reaction Journal of Catalysis. ,vol. 149, pp. 70- 80 ,(1994) , 10.1006/JCAT.1994.1273
T TAKESHITA, Rare earth intermetallics as synthetic ammonia catalysts Journal of Catalysis. ,vol. 44, pp. 236- 243 ,(1976) , 10.1016/0021-9517(76)90394-8