Electron-donating behaviour of aliphatic carboxylic acids in the photoreaction with 1,2,4,5-tetracyanobenzene
作者： Kazuo Tsujimoto , Nobuhisa Nakao , Mamoru Ohashi
DOI: 10.1039/C39920000366
关键词: Alkylation 、 Nitrile 、 Excited state 、 Acetonitrile 、 Aliphatic compound 、 Chemistry 、 Carboxylic acid 、 Irradiation 、 Electron transfer 、 Photochemistry
摘要: Irradiation of an acetonitrile solution 1,2,4,5-tetracyanobenzene with aliphatic carboxylic acids gives 2,4,5-tricyanoalkylbenzenes efficiently; electron transfer from the to excited tetracyanobenzene is essential.
rsc.org
sci-hub.se 参考文章(2)
Izaak M. Kolthoff, Miran K. Chantooni, Sadhana. Bhowmik, Dissociation constants of uncharged and monovalent cation acids in dimethyl sulfoxide Journal of the American Chemical Society. ,vol. 90, pp. 23- 28 ,(1968) , 10.1021/JA01003A005
Jacqueline Libman, LIGHT INDUCED CHARGE TRANSFER PROCESSES, THE PHOTOCHEMICAL BEHAVIOR OF 1-CYANONAPHTHALENE IN THE PRESENCE OF PHENYLACETIC ACID DERIVATIVES Journal of the American Chemical Society. ,vol. 97, pp. 4139- 4141 ,(1975) , 10.1021/JA00847A051