On the dynamic mechanical behavior of nylon 66

作者: J. H. Dumbleton , T. Murayama

DOI: 10.1007/BF02085563

关键词: PerpendicularTriclinic crystal systemPolymerAnnealing (metallurgy)Composite materialNylon 66Materials scienceGlass transitionHexagonal phaseYoung's modulus

摘要: The dynamic mechanical properties of nylon 66 films and fibers have been examined, as a function annealing drawing, with Vibron viscoelastometer. It is found that the α′ transition little affected by treatments, but increase in orientation causes to move higher temperature. Experiments, X-ray diffraction samples at elevated temperatures, lead conclusion triclinic hexagonal phase change does not contribute significantly transition. Samples cut parallel perpendicular drawing direction film, used show curves tensile modulus versus temperature, for directions, cross neighborhood This observation discussed relation suggestion glass 66.

参考文章(20)
D. A. Zaukelies, Observation of Slip In Nylon 66 and 610 and Its Interpretation in Terms of a New Model Journal of Applied Physics. ,vol. 33, pp. 2797- 2803 ,(1962) , 10.1063/1.1702552
Harry J. Kolb, Emmette F. Izard, Dilatometric Studies of High Polymers. I. Second‐Order Transition Temperature Journal of Applied Physics. ,vol. 20, pp. 564- 571 ,(1949) , 10.1063/1.1698426
Motowo Takayanagi, Kiyohisa Imada, Tisato Kajiyama, Mechanical properties and fine structure of drawn polymers Journal of Polymer Science Part C: Polymer Symposia. ,vol. 15, pp. 263- 281 ,(2007) , 10.1002/POLC.5070150118
A.E Woodward, J.A Sauer, C.W Deeley, D.E Kline, The dynamic mechanical behavior of some nylons Journal of Colloid Science. ,vol. 12, pp. 363- 377 ,(1957) , 10.1016/0095-8522(57)90036-3
Paden F. Dismore, W. O. Statton, Chain folding in oriented nylon 66 fibers Journal of Polymer Science Part C: Polymer Symposia. ,vol. 13, pp. 133- 148 ,(2007) , 10.1002/POLC.5070130111
A. E. Woodward, J. M. Crissman, J. A. Sauer, Investigations of the dynamic mechanical properties of some polyamides Journal of Polymer Science. ,vol. 44, pp. 23- 34 ,(1960) , 10.1002/POL.1960.1204414303
J. H. Dumbleton, T. Murayama, Temperature dependence of the dynamic mechanical behavior of poly(ethylene terephthalate) fibers Kolloid-Zeitschrift & Zeitschrift für Polymere. ,vol. 220, pp. 41- 48 ,(1967) , 10.1007/BF02086055
J. H. Dumbleton, T. Murayama, J. P. Bell, On the dynamic mechanical behaviour of drawn poly(ethylene terephthalate) fibers Kolloid-Zeitschrift & Zeitschrift für Polymere. ,vol. 228, pp. 54- 58 ,(1968) , 10.1007/BF02125764
R. F. Boyer, R. S. Spencer, Thermal Expansion and Second‐Order Transition Effects in High Polymers: Part I. Experimental Results Journal of Applied Physics. ,vol. 15, pp. 398- 405 ,(1944) , 10.1063/1.1707444
E. SEGERMAN, P. G. STERN, Two-phase Model for Structure of Polymers Nature. ,vol. 210, pp. 1258- 1259 ,(1966) , 10.1038/2101258A0