Brownian motion description of activation energies from NMR-relaxation times for rotating molecular-groups
作者： O. Edholm , C. Blomberg
DOI: 10.1016/0301-0104(81)85094-X
关键词: Limit (mathematics) 、 Brownian motion 、 Physics 、 Atomic physics 、 Quantum mechanics 、 Diffusion equation 、 Activation energy 、 Eigenvalues and eigenvectors 、 Eigenfunction 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: Abstract A general formula is derived (containing eigenvalues and eigenfunctions of some diffusion equation) for activation energies from NMR-relaxation times rotating molecular groups. Numerical calculations a trigonometric three well potential in the strong damping (Smoluchowski) limit show that there may be considerable difference between energy barrier height. In low fairly good agreement.
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