Non-radiative de-excitation of deep centres

作者: A.M. Stoneham , R.H. Bartram

DOI: 10.1016/0038-1101(78)90201-0

关键词: ExcitationPotential energyAtomic physicsLattice (order)Adiabatic processRadiative transferPopulationChemistryExcited stateGround state

摘要: We develop a quantitative theory of the ratio R radiative to non-radiative de-excitation based on Dexter-Klick-Russell criterion for occurrence luminescence. The model invokes three essential elements: promoting mode, an accepting and set lattice modes which ultimately absorb vibrational energy. is determined by relative population relaxed excited ground states. show that Rnx(a)/ng(a), where nx(a) ng(a) are numbers quanta in mode associated with state state, respectively, at crossing their adiabatic potential energy curves. result consistent experiment.

参考文章(9)
Non-Adiabatic Crossing of Energy Levels Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 137, pp. 696- 702 ,(1932) , 10.1098/RSPA.1932.0165
Dissociation of Excited Diatomic Molecules by External Perturbations Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 140, pp. 660- 668 ,(1933) , 10.1098/RSPA.1933.0095
R.H. Bartram, A.M. Stoneham, On the luminescence and absence of luminescence of F centers Solid State Communications. ,vol. 17, pp. 1593- 1598 ,(1975) , 10.1016/0038-1098(75)91003-0
Karl F. Freed, Joshua Jortner, Multiphonon Processes in the Nonradiative Decay of Large Molecules The Journal of Chemical Physics. ,vol. 52, pp. 6272- 6291 ,(1970) , 10.1063/1.1672938
D. L. Dexter, C. C. Klick, G. A. Russell, Criterion for the Occurrence of Luminescence Physical Review. ,vol. 100, pp. 603- 605 ,(1955) , 10.1103/PHYSREV.100.603
A. D. Brailsford, Tai Yup Chang, Nonradiative Decay of Individual Vibronic Levels in Large Molecules The Journal of Chemical Physics. ,vol. 53, pp. 3108- 3113 ,(1970) , 10.1063/1.1674455
M C M O'Brien, The dynamic jahn-teller effect with many frequencies: a simple approach to a complicated problem Journal of Physics C: Solid State Physics. ,vol. 5, pp. 2045- 2063 ,(1972) , 10.1088/0022-3719/5/15/019
A. M. Stoneham, II. Non-radiative processes in insulators and semiconductors Philosophical Magazine. ,vol. 36, pp. 983- 997 ,(1977) , 10.1080/14786437708239773