Electrostatic trapping of ammonia molecules

作者: Hendrick L. Bethlem , Giel Berden , Floris M. H. Crompvoets , Rienk T. Jongma , André J. A. van Roij

DOI: 10.1038/35020030

关键词: Optical tweezersRange (particle radiation)MoleculeElectric fieldAtomic physicsCaesiumTrappingChemistryChemical polarityChemical physicsParamagnetism

摘要: The ability to cool and slow atoms with light for subsequent trapping1,2,3 allows investigations of the properties interactions trapped in unprecedented detail. By contrast, complex structure molecules prohibits this type manipulation, but magnetic trapping calcium hydride thermalized ultra-cold buffer gas4 optical caesium dimers5 generated from have been reported. However, these methods depend on target being paramagnetic or able form through association amenable laser cooling6,7,8, respectively, thus restricting range species that can be studied. Here we describe slowing an adiabatically cooled beam deuterated ammonia by time-varying inhomogeneous electric fields9,10 loading into electrostatic trap. We are trap state-selected a density 106 cm-3 volume 0.25 cm3 at temperatures below 0.35 K. observe pronounced oscillations caused rapid switching fields during Our findings illustrate polar efficiently trapped, providing opportunity study collisions collective quantum effects wide molecular systems11,12,13,14.

参考文章(24)
John M. Doyle, Bretislav Friedrich, Molecules are cool Nature. ,vol. 401, pp. 749- 751 ,(1999) , 10.1038/44479
J.T. Bahns, P.L. Gould, W.C. Stwalley, Formation of Cold (T ⩽ 1 K) Molecules Advances in Atomic Molecular and Optical Physics. ,vol. 42, pp. 171- 224 ,(2000) , 10.1016/S1049-250X(08)60187-1
Carl J Williams, Paul S Julienne, Molecules at Rest Science. ,vol. 287, pp. 986- 987 ,(2000) , 10.1126/SCIENCE.287.5455.986
Jonathan D. Weinstein, Robert deCarvalho, Thierry Guillet, Bretislav Friedrich, John M. Doyle, Magnetic trapping of calcium monohydride molecules at millikelvin temperatures Nature. ,vol. 395, pp. 148- 150 ,(1998) , 10.1038/25949
Roahn Wynar, RS Freeland, DJ Han, C Ryu, DJ Heinzen, Molecules in a bose-einstein condensate Science. ,vol. 287, pp. 1016- 1019 ,(2000) , 10.1126/SCIENCE.287.5455.1016
Hendrick L. Bethlem, Giel Berden, André J. A. van Roij, Floris M. H. Crompvoets, Gerard Meijer, Trapping neutral molecules in a traveling potential well. Physical Review Letters. ,vol. 84, pp. 5744- 5747 ,(2000) , 10.1103/PHYSREVLETT.84.5744
Hendrick L. Bethlem, Giel Berden, Gerard Meijer, Decelerating Neutral Dipolar Molecules Physical Review Letters. ,vol. 83, pp. 1558- 1561 ,(1999) , 10.1103/PHYSREVLETT.83.1558
A. N. Nikolov, E. E. Eyler, X. T. Wang, J. Li, H. Wang, W. C. Stwalley, P. L. Gould, OBSERVATION OF ULTRACOLD GROUND-STATE POTASSIUM MOLECULES Physical Review Letters. ,vol. 82, pp. 703- 706 ,(1999) , 10.1103/PHYSREVLETT.82.703
Suketu R. Gandhi, Richard B. Bernstein, Focusing and state selection of NH3 and OCS by the electrostatic hexapole via first‐ and second‐order Stark effects The Journal of Chemical Physics. ,vol. 87, pp. 6457- 6467 ,(1987) , 10.1063/1.453427
Bretislav Friedrich, Robert deCarvalho, Jinha Kim, David Patterson, Jonathan D. Weinstein, John M. Doyle, Towards magnetic trapping of molecules Journal of the Chemical Society, Faraday Transactions. ,vol. 94, pp. 1783- 1791 ,(1998) , 10.1039/A708859K