Single-Walled Carbon Nanotubes Modified with Pd Nanoparticles : Unique Building Blocks for High-Performance, Flexible Hydrogen Sensors

作者: Yugang Sun , H. Hau Wang , Minggang Xia

DOI: 10.1021/JP076965N

关键词: NanotechnologyPd nanoparticlesHydrogen sensorCarbon nanotubeComposite materialDurabilityHydrogenMaterials scienceBent molecular geometryBendingPalladium

摘要: High-performance hydrogen sensors with excellent mechanical flexibility and durability have been fabricated on thin plastic sheets the use of high-quality semiconducting single-walled carbon nanotubes decorated discrete Pd nanoparticles. These exhibit sensing performance much higher than that traditional ones built precious pure palladium structures rigid substrates. For example, sensitivity typical flexible is in range 100−150% (based resistance change sensors) for 0.1% dry air at room temperature. The response times are typically less 15 s 1% hydrogen, can be completely recovered within 5 min without hydrogen. detect concentrations as low 100 ppm (0.01%). Experimental results indicate as-fabricated devices operate well even when they bent to a curved geometry bending radii down 2 mm after treated 1000 o...

参考文章(71)
Yente Chao, Sheng Yao, William J Buttner, Joseph R Stetter, Amperometric sensor for selective and stable hydrogen measurement Sensors and Actuators B-chemical. ,vol. 106, pp. 784- 790 ,(2005) , 10.1016/J.SNB.2004.09.042
N. W. Shi Kam, M. O'Connell, J. A. Wisdom, H. Dai, Carbon nanotubes as multifunctional biological transporters and near-infrared agents for selective cancer cell destruction. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 102, pp. 11600- 11605 ,(2005) , 10.1073/PNAS.0502680102
Shinji Nakagomi, Kohji Okuda, Yoshihiro Kokubun, Electrical properties dependent on H2 gas for new structure diode of Pt–thin WO3–SiC Sensors and Actuators B-chemical. ,vol. 96, pp. 364- 371 ,(2003) , 10.1016/S0925-4005(03)00570-7
Coskun Kocabas, Moonsub Shim, John A Rogers, None, Spatially selective guided growth of high-coverage arrays and random networks of single-walled carbon nanotubes and their integration into electronic devices. Journal of the American Chemical Society. ,vol. 128, pp. 4540- 4541 ,(2006) , 10.1021/JA0603150
L.M. Lechuga, A. Calle, D. Golmayo, F. Briones, Hydrogen sensor based on a Pt/GaAs Schottky diode Sensors and Actuators B-chemical. ,vol. 4, pp. 515- 518 ,(1991) , 10.1016/0925-4005(91)80161-C
Heng-Yong Nie, Yasuo Nannichi, Pd-on-GaAs Schottky Contact: Its Barrier Height and Response to Hydrogen Japanese Journal of Applied Physics. ,vol. 30, pp. 906- 913 ,(1991) , 10.1143/JJAP.30.906
Francisco J. Ibañez, Francis P. Zamborini, Ozone- and Thermally Activated Films of Palladium Monolayer-Protected Clusters for Chemiresistive Hydrogen Sensing Langmuir. ,vol. 22, pp. 9789- 9796 ,(2006) , 10.1021/LA0617309
X Bévenot, A Trouillet, C Veillas, H Gagnaire, M Clément, Surface plasmon resonance hydrogen sensor using an optical fibre Measurement Science and Technology. ,vol. 13, pp. 118- 124 ,(2002) , 10.1088/0957-0233/13/1/315
Thomas M. Day, Patrick R. Unwin, Neil R. Wilson, Julie V. Macpherson, Electrochemical Templating of Metal Nanoparticles and Nanowires on Single-Walled Carbon Nanotube Networks Journal of the American Chemical Society. ,vol. 127, pp. 10639- 10647 ,(2005) , 10.1021/JA051320R