A biosensor based on gold nanoparticles, dihexadecylphosphate, and tyrosinase for the determination of catechol in natural water.
作者： Fernando Campanhã Vicentini , Lívia L.C. Garcia , Luiz C.S. Figueiredo-Filho , Bruno C. Janegitz , Orlando Fatibello-Filho
DOI: 10.1016/J.ENZMICTEC.2015.12.004
关键词: Colloidal gold 、 Biosensor 、 Chemistry 、 Nuclear chemistry 、 Amperometry 、 Catechol 、 Cyclic voltammetry 、 Detection limit 、 Tyrosinase 、 Glutaraldehyde 、 Analytical chemistry
摘要: In this work, a biosensor using glassy carbon electrode modified with gold nanoparticles (AuNPs) and tyrosinase (Tyr) within dihexadecylphosphate film is proposed. Cystamine glutaraldehyde crosslinking agents were used as support for Tyr immobilization. The proposed was characterized by scanning electron microscopy (SEM), transmission (TEM), cyclic voltammetry in the presence of catechol. determination catechol carried out amperometry presented linear concentration range from 2.5×10(-6) to 9.5×10(-5)molL(-1) detection limit 1.7×10(-7)molL(-1). developed showed good repeatability stability. Moreover, novel amperometric method successfully applied natural water samples. results agreement 95% confidence level those obtained official spectrophotometric method.
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sci-hub.se 参考文章(57)
Jack L. Smith, R.C. Krueger, Separation and purification of the phenolases of the common mushroom. Journal of Biological Chemistry. ,vol. 237, pp. 1121- 1128 ,(1962) , 10.1016/S0021-9258(18)60294-7
V. Carralero Sanz, Ma Luz Mena, A. González-Cortés, P. Yáñez-Sedeño, J.M. Pingarrón, Development of a tyrosinase biosensor based on gold nanoparticles-modified glassy carbon electrodes: Application to the measurement of a bioelectrochemical polyphenols index in wines Analytica Chimica Acta. ,vol. 528, pp. 1- 8 ,(2005) , 10.1016/J.ACA.2004.10.007
Christopher M. A. Brett, Ana Maria Oliveira Brett, Electrochemistry: Principles, Methods, and Applications ,(1993)
Andrew Eaton, A.E. Greenberg, Lenore S. Clesceri, Standard methods for the examination of water and wastewater Published in <b>1998</b> in Washington DC) by American public health association. ,(1992)
Eliane P. Cipolatti, María José A. Silva, Manuela Klein, Vivian Feddern, Maria Manuela C. Feltes, J. Vladimir Oliveira, Jorge L. Ninow, Débora de Oliveira, Current status and trends in enzymatic nanoimmobilization Journal of Molecular Catalysis B-enzymatic. ,vol. 99, pp. 56- 67 ,(2014) , 10.1016/J.MOLCATB.2013.10.019
Susana Campuzano, Beatriz Serra, Marı́a Pedrero, F.Javier Manuel de Villena, José M. Pingarrón, Amperometric flow-injection determination of phenolic compounds at self-assembled monolayer-based tyrosinase biosensors Analytica Chimica Acta. ,vol. 494, pp. 187- 197 ,(2003) , 10.1016/S0003-2670(03)00919-X
Farshad Kheiri, Reza Emamali Sabzi, Elham Jannatdoust, Hassan Sedghi, Acetone extracted propolis as a novel membrane and its application in phenol biosensors: the case of catechol Journal of Solid State Electrochemistry. ,vol. 15, pp. 2593- 2599 ,(2011) , 10.1007/S10008-010-1250-2
Yu-Chin Lin, Bang-Ying Yu, Wei-Chun Lin, Szu-Hsian Lee, Che-Hung Kuo, Jing-Jong Shyue, Tailoring the surface potential of gold nanoparticles with self-assembled monolayers with mixed functional groups joint international conference on information sciences. ,vol. 340, pp. 126- 130 ,(2009) , 10.1016/J.JCIS.2009.08.014
Sarah Ward Jones, Richard Compton, Fabrication and Applications of Nanoparticle-Modified Electrodes in Stripping Analysis Current Analytical Chemistry. ,vol. 4, pp. 177- 182 ,(2008) , 10.2174/157341108784911370
Irene Carpani, Erika Scavetta, Domenica Tonelli, Amperometric Glucose Biosensors Based on Glassy Carbon and SWCNT- Modified Glassy Carbon Electrodes Electroanalysis. ,vol. 20, pp. 84- 90 ,(2008) , 10.1002/ELAN.200704054