Anionic reduced forms of electron-deficient arenes in reactions with C–C bond formation
作者： T A Vaganova , E V Panteleeva , V D Shteingarts
DOI: 10.1070/RC2008V077N07ABEH003776
关键词: Organic chemistry 、 Chemistry 、 Computational chemistry 、 Synthon 、 Bond formation 、 Reaction mechanism 、 Reagent 、 Electron
摘要: The state-of-the-art research related to the use of stable anionic reduced forms (radical anions, dianions, cyclohexadienyl anions) electron-deficient arenes as synthons for design short synthetic pathways from basic reagents compounds difficult prepare is analysed. role these models study competition polar and single-electron reaction mechanisms, especially elucidation relevant structural features, considered.
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