Synthesis and spectroscopic characterization of metal complexes with naphthofuran-2-carbohydrazide Schiff 's base
作者： Shashidhar , K Shivakumar , P Vithal Reddy , MB Halli , None
DOI: 10.1080/00958970601112051
关键词: Conductance 、 Denticity 、 Chemistry 、 Benzaldehyde 、 Carbohydrazide 、 Magnetic susceptibility 、 Medicinal chemistry 、 Proton NMR 、 Inorganic chemistry 、 Metal 、 Base (chemistry)
摘要: Two Schiff-base ligands (I) naphthofuro-[phenylmethine]carbohydrazone [NPMC] and (II) naphthofruo-[3,4-dimethoxyphenylmethine]carbohydrazone [NDMeOPMC] were prepared by reaction between naphthofuran-2-carbohydrazone benzaldehyde or 3,4-dihydroxybenzaldehyde, respectively. Both are bidentate coordinating through carboxy oxygen azomethine nitrogen atoms. Complexes of the type MLX n obtained. where M = Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), UO2(II) Th(IV), L = [NPMC] X = Cl2 for Co(II), Cd(II) Hg(II) complexes, X = NO3, n = 2 complexes n = 4 Th(IV) complexes. All characterized IR, electronic, 1H NMR, ESR, conductance data magnetic susceptibility measurements.
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