A Mathematical Model of a Sealed Nickel‐Cadmium Battery

作者: Deyuan Fan , Ralph E. White

DOI: 10.1149/1.2085532

关键词: ChemistryElectrodeElectrochemistryMathematical modelNickel–cadmium batteryThermodynamicsAnalytical chemistryElectric chargeElectrolyteBattery (electricity)Electrochemical cell

摘要: This paper presents a mathematical model for the charge and discharge of sealed nickel-cadmium (Ni- Cd) battery. The is used to study effect transport properties electrolyte kinetic parameters electrode reactions on cell performance during period. can also be demonstrate changes cycling. Some comparisons between predictions experimental results indicate that appear fit data well. Sensitivity analyses illustrate battery operates under activation control. It shown theoretically oxygen generated positive reduced electrochemically negative electrode.

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Ralph E. White, Electrochemical Cell Design ,(2011)