作者: Deyuan Fan , Ralph E. White
DOI: 10.1149/1.2085532
关键词: Chemistry 、 Electrode 、 Electrochemistry 、 Mathematical model 、 Nickel–cadmium battery 、 Thermodynamics 、 Analytical chemistry 、 Electric charge 、 Electrolyte 、 Battery (electricity) 、 Electrochemical cell
摘要: This paper presents a mathematical model for the charge and discharge of sealed nickel-cadmium (Ni- Cd) battery. The is used to study effect transport properties electrolyte kinetic parameters electrode reactions on cell performance during period. can also be demonstrate changes cycling. Some comparisons between predictions experimental results indicate that appear fit data well. Sensitivity analyses illustrate battery operates under activation control. It shown theoretically oxygen generated positive reduced electrochemically negative electrode.