Deuterium isotope effects on one-bond carbon, hydrogen coupling constants
关键词: Chemistry 、 Organic molecules 、 Deuterium 、 Coupling constant 、 Nuclear chemistry 、 Physical chemistry 、 Carbon 、 Deuterium NMR 、 Chemical shift 、 Hydrogen 、 Kinetic isotope effect 、 General Materials Science 、 General chemistry
摘要: Small, negative deuterium isotope effects on 1J(CH) have been found for a variety of simple organic molecules. These new experimental data support theoretical calculations and suggestions based previous imprecise measurements. The upon the 13C chemical shifts were also measured with high precision.
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