Physical, optical and luminescence properties of the Dy3+doped barium borophosphate glasses

作者: Sujita Karki , C.R. Kesavulu , H.J. Kim , J. Kaewkhao , N. Chanthima

DOI: 10.1016/J.JNONCRYSOL.2019.119483

关键词: DysprosiumIonChromaticityRadiative transferBariumAnalytical chemistryOxideMaterials scienceLuminescenceDoping

摘要: Abstract Barium borophosphate glasses doped with dysprosium oxide had been fabricated by conventional melt quenching technique using the chemical composition of: (25BaO: 5B 2 O 3 : 70-xP 5 xDy )), where (x = 0.2, 0.4, 0.6, 0.8 and 1.0, mol%) (BaBPDy). The physical, optical luminescence properties are studied for possibility of as a white materials solid-state light emitting devices. Judd-Ofelt (JO) theory is applied to study radiative level Dy 3+ ions. effect concentration due increase in ions discussed details. lifetime all BaBPDy glass bi-exponential nature, which present work. This non-exponential nature decay curve was fitted well-known Inokuti-Hirayama (IH) model S= 6, indicating that energy transfer process dipole-dipole type. chromaticity co-ordinate(x, y) evaluated from spectra its application has analyzed.

参考文章(41)
Fouad El-Diasty, M. Abdel-Baki, F. A. Moustafa, A. M. Fayad, Role of Mixed Valence Effect and Orbital Hybridization on Molar Volume of Heavy Metal Glass for Ionic Conduction Pathways Augmentation American Journal of Materials Science. ,vol. 4, pp. 119- 126 ,(2014)
Hiromichi Takebe, Takashi Harada, Makoto Kuwabara, Effect of B2O3 addition on the thermal properties and density of barium phosphate glasses Journal of Non-crystalline Solids. ,vol. 352, pp. 709- 713 ,(2006) , 10.1016/J.JNONCRYSOL.2005.11.066
W. T. Carnall, P. R. Fields, K. Rajnak, Electronic Energy Levels of the Trivalent Lanthanide Aquo Ions. III. Tb3 Journal of Chemical Physics. ,vol. 49, pp. 4447- 4449 ,(1968) , 10.1063/1.1669895
S. Tuscharoen, J. Kaewkhao, P. Limkitjaroenporn, P. Limsuwan, W. Chewpraditkul, Improvement of BaO:B2O3:Fly ash glasses: Radiation shielding, physical and optical properties Annals of Nuclear Energy. ,vol. 49, pp. 109- 113 ,(2012) , 10.1016/J.ANUCENE.2012.05.017
C.R. Kesavulu, C.K. Jayasankar, White light emission in Dy3+-doped lead fluorophosphate glasses Materials Chemistry and Physics. ,vol. 130, pp. 1078- 1085 ,(2011) , 10.1016/J.MATCHEMPHYS.2011.08.037
R. Vijayakumar, G. Venkataiah, K. Marimuthu, White light simulation and luminescence studies on Dy3+ doped Zinc borophosphate glasses Physica B-condensed Matter. ,vol. 457, pp. 287- 295 ,(2015) , 10.1016/J.PHYSB.2014.10.003
N. Kiran, A. Suresh Kumar, White light emission from Dy3+ doped sodium–lead borophosphate glasses under UV light excitation Journal of Molecular Structure. ,vol. 1054, pp. 6- 11 ,(2013) , 10.1016/J.MOLSTRUC.2013.09.023
Christian K. Jørgensen, Renata Reisfeld, Judd-Ofelt parameters and chemical bonding☆ Journal of The Less Common Metals. ,vol. 93, pp. 107- 112 ,(1983) , 10.1016/0022-5088(83)90454-X
C.K. Jayasankar, E. Rukmini, Optical properties of Sm3+ ions in zinc and alkali zinc borosulphate glasses Optical Materials. ,vol. 8, pp. 193- 205 ,(1997) , 10.1016/S0925-3467(97)00021-9