Cyclopentenone Formation from Alkyne-Cobalt Complexes
作者： P. L. Pauson
DOI: 10.1007/978-3-642-73196-9_12
关键词: Silyl ether 、 Propargyl alcohol 、 Chemistry 、 Vinyl ether 、 Yield (chemistry) 、 Cyclopentenone 、 Alkyne 、 Medicinal chemistry 、 Ethyl vinyl ether 、 Cobalt
摘要: Virtually all alkynes react smoothly and under mild conditions with octacarbonyldicobalt to yield complexes of the type (1). When treated alkenes such give cyclopentenone derivatives (2), a reaction which we call “Khand reaction” after my late coworker Dr. I. U. Khand, who not only first observed this transformation, but also subjected it systematic study.
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