Metallacyclobutadiene versus metallatetrahedrane structures for Cl3MoC3H3 complexes

作者: Eric V. Anslyn , Mark J. Brusich , William A. Goddard

DOI: 10.1021/OM00091A018

关键词: Gaussian orbitalConfiguration interactionChemistryCovalent bondComputational chemistryMetallacycleReactivity (chemistry)EnergeticsCrystallographyRing (chemistry)Charge density

摘要: Conclusion Our results present an easy access to electron-rich (jy4-hydrocarbon) iron complexes via FeCl2 (PR3)„interme-diates, magnesium, and halogenated substrates. This …

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