Photovoltaic properties of poly(benzothiadiazole-thiophene-co-bithiophene) as donor in polymer solar cells
作者： Guangjin Zhao , Youjun He , Chang He , Haijun Fan , Yun Zhao
DOI: 10.1016/J.SOLMAT.2010.10.007
关键词: Thiophene 、 Chemical engineering 、 Side chain 、 Polymer solar cell 、 Polymer chemistry 、 Materials science 、 Electron donor 、 Electron acceptor 、 Monomer 、 Organic solar cell 、 Acceptor
摘要: Abstract We report the photovoltaic properties of a D–A copolymer, poly(benzothiadiazole-thiophene-co-bithiophene) (PBTTbT), containing donor (D) unit oligothiophene with hexyl side chain and acceptor (A) 2,1,3-benzothiadiazole (BT) methyl chain. The geometry, electronic absorption spectroscopic bithiophene-benzothiadiazole-thiophene monomer (M1) polymer were investigated theoretically by density functional theory (DFT) method for deep understanding relationship structure polymer. Polymer solar cells (PSCs) fabricated PBTTbT as an electron blended [6,6]-phenyl-C71-butyric acid ester (PC 70 BM) acceptor. power conversion efficiency (PCE) PSC is 0.87% optimized PBTTbT:PC BM weight ratio 1:3, under illumination AM 1.5, 100 mW/cm 2 . With additive 1% 1,8-dioctanedithiol thermal annealing at 130 °C 15 min, PCE device was improved to 1.98%. improvement ascribed better morphology active layer annealing.
elsevier.com
sci-hub.se 参考文章(61)
Frederik C. Krebs, Torben D. Nielsen, Jan Fyenbo, Mads Wadstrøm, Marie S. Pedersen, Manufacture, integration and demonstration of polymer solar cells in a lamp for the “Lighting Africa” initiative Energy and Environmental Science. ,vol. 3, pp. 512- 525 ,(2010) , 10.1039/B918441D
Katsuyuki Naito, Masatoshi Sakurai, Syun Egusa, Molecular Design, Syntheses, and Physical Properties of Nonpolymeric Amorphous Dyes for Electron Transport Journal of Physical Chemistry A. ,vol. 101, pp. 2350- 2357 ,(1997) , 10.1021/JP963233E
Frederik C. Krebs, Suren A. Gevorgyan, Jan Alstrup, A roll-to-roll process to flexible polymer solar cells: model studies, manufacture and operational stability studies Journal of Materials Chemistry. ,vol. 19, pp. 5442- 5451 ,(2009) , 10.1039/B823001C
Erjun Zhou, Shimpei Yamakawa, Keisuke Tajima, Chunhe Yang, Kazuhito Hashimoto, Synthesis and Photovoltaic Properties of Diketopyrrolopyrrole-Based Donor−Acceptor Copolymers Chemistry of Materials. ,vol. 21, pp. 4055- 4061 ,(2009) , 10.1021/CM901487F
Frederik C. Krebs, Jan Fyenbo, Mikkel Jørgensen, Product integration of compact roll-to-roll processed polymer solar cell modules: methods and manufacture using flexographic printing, slot-die coating and rotary screen printing Journal of Materials Chemistry. ,vol. 20, pp. 8994- 9001 ,(2010) , 10.1039/C0JM01178A
Youjun He, Hsiang-Yu Chen, Jianhui Hou, Yongfang Li, Indene−C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells Journal of the American Chemical Society. ,vol. 132, pp. 1377- 1382 ,(2010) , 10.1021/JA908602J
Jae Kwan Lee, Wan Li Ma, Christoph J. Brabec, Jonathan Yuen, Ji Sun Moon, Jin Young Kim, Kwanghee Lee, Guillermo C. Bazan, Alan J. Heeger, Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells Journal of the American Chemical Society. ,vol. 130, pp. 3619- 3623 ,(2008) , 10.1021/JA710079W
Erjun Zhou, Motoshi Nakamura, Takeshi Nishizawa, Yue Zhang, Qingshuo Wei, Keisuke Tajima, Chunhe Yang, Kazuhito Hashimoto, Synthesis and Photovoltaic Properties of a Novel Low Band Gap Polymer Based on N-Substituted Dithieno[3,2-b:2',3'-d]pyrrole Macromolecules. ,vol. 41, pp. 8302- 8305 ,(2008) , 10.1021/MA802052W
V.D. Mihailetchi, J.K.J. van Duren, P.W.M. Blom, J.C. Hummelen, R.A.J. Janssen, J.M. Kroon, M.T. Rispens, W.J.H. Verhees, M.M. Wienk, Electron transport in a methanofullerene Advanced Functional Materials. ,vol. 13, pp. 43- 46 ,(2003) , 10.1002/ADFM.200390004
Chih-Ping Chen, Shu-Hua Chan, Teng-Chih Chao, Ching Ting, Bao-Tsan Ko, Low-bandgap poly(thiophene-phenylene-thiophene) derivatives with broaden absorption spectra for use in high-performance bulk-heterojunction polymer solar cells. Journal of the American Chemical Society. ,vol. 130, pp. 12828- 12833 ,(2008) , 10.1021/JA801877K