Quantitative determination of the O(P3) density via visible cavity-enhanced spectroscopy

作者: Manish Gupta , Thomas Owano , Douglas Baer , Anthony O’Keefe

DOI: 10.1063/1.2408655

关键词: Absorption (electromagnetic radiation)Analytical chemistryInductively coupled plasmaUltraviolet visible spectroscopyOptical cavityAtomGround stateChemistryPlasma diagnosticsSpectroscopy

摘要: A simple method has been developed to quantitatively measure the ground state oxygen atom, O(P3), density. The technique exploits cavity-enhanced spectroscopy probe relatively weak O(D1)←O(P13) transition near 636nm. O(P13) densities of approximately 3.4×1014at.∕cm3 were measured in an inductively coupled plasma produced within a high-finesse optical cavity, and minimum detectable atom density 1.3×1012at.∕cm3 was determined. absorption profile yielded translational temperature 453K. can be readily extended other atomic species.

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