The nature of the nitrate in the TBP solvates M(NO3)3·3TBP, M(NO3)4·2TBP and MO2(NO3)2·2TBP☆

作者: J.R. Ferraro

DOI: 10.1016/0022-1902(59)80124-X

关键词: ChemistryGroup (periodic table)InfraredSpectral lineNitrateCrystallographySymmetry (geometry)Inorganic chemistry

摘要: Abstract An examination of the infra-red spectra TBP solvates M(NO3)3·3TBP, M(NO3)4·2TBP and MO2(NO3)2·2TBP has been made, compared with corresponding hydrates. It is observed that a considerable decrease in symmetry nitrate group occurred going from hydrates to solvates.

参考文章(19)
K. Alcock, G.F. Best, E. Hesford, H.A.C. McKay, Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates—V: Further results for the tetra- and hexavalent actinide nitrates Journal of Inorganic and Nuclear Chemistry. ,vol. 6, pp. 328- 333 ,(1958) , 10.1016/0022-1902(58)80116-5
Taichi Sato, THE EXTRACTION OF URANYL NITRATE FROM NITRIC ACID SOLUTIONS BY TRIBUTYL PHOSPHATE Journal of Inorganic and Nuclear Chemistry. ,vol. 6, pp. 334- 337 ,(1958) , 10.1016/0022-1902(58)80117-7
E. Hesford, H. A. C. McKay, The extraction of nitrates by tri-n-butyl phosphate (TBP). Part 3.—Extraction at trace concentrations Trans. Faraday Soc.. ,vol. 54, pp. 573- 586 ,(1958) , 10.1039/TF9585400573
D.F. Peppard, G.W. Mason, J.L. Maier, Interrelationships in the solvent extraction behaviour of scandium, thorium, and zirconium in certain tributyl phosphate-mineral acid systems Journal of Inorganic and Nuclear Chemistry. ,vol. 3, pp. 215- 228 ,(1956) , 10.1016/0022-1902(56)80022-5
E. Hesford, H.A.C. McKay, D. Scargill, Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates—IV Thorium nitrate Journal of Inorganic and Nuclear Chemistry. ,vol. 4, pp. 321- 325 ,(1957) , 10.1016/0022-1902(57)80014-1
T. V. Healy, H. A. C. Mckay, Complexes between tributyl phosphate and inorganic nitrates Recueil des Travaux Chimiques des Pays-Bas. ,vol. 75, pp. 730- 736 ,(2010) , 10.1002/RECL.19560750623
Leonard I. Katzin, John R. Ferraro, W. W. Wendlandt, R. L. McBeth, The Relations of Thorium Nitrate and Certain Organic Solvents.1 The Coördination Number of Th4 Journal of the American Chemical Society. ,vol. 78, pp. 5139- 5144 ,(1956) , 10.1021/JA01601A001
F. A. Miller, C. H. Wilkins, Infrared Spectra and Characteristic Frequencies of Inorganic Ions Analytical Chemistry. ,vol. 24, pp. 1253- 1294 ,(1952) , 10.1021/AC60068A007
T. V. Healy, H. A. C. McKay, The extraction of nitrates by tri-n-butyl phosphate (TBP). Part 2.—The nature of the TBP phase Trans. Faraday Soc.. ,vol. 52, pp. 633- 642 ,(1956) , 10.1039/TF9565200633
D. F. Peppard, P. R. Gray, M. M. Markus, The Actinide—Lanthanide Analogy as Exemplified by Solvent Extraction Behavior Journal of the American Chemical Society. ,vol. 75, pp. 6063- 6064 ,(1953) , 10.1021/JA01119A528