Solid-State Redox Switching of Magnetic Exchange and Electronic Conductivity in a Benzoquinoid-Bridged MnII Chain Compound
作者： Ie-Rang Jeon , Lei Sun , Bogdan Negru , Richard P. Van Duyne , Mircea Dincă
DOI: 10.1021/JACS.6B02485
关键词: Raman spectroscopy 、 Ligand 、 Chain (algebraic topology) 、 Chemistry 、 Metalation 、 Electrochromism 、 Redox 、 Inorganic chemistry 、 Electron transfer 、 Crystallography 、 Absorption spectroscopy
摘要: We demonstrate that incorporation of a redox-active benzoquinoid ligand into one-dimensional chain compound can give rise to material exhibits simultaneous solid-state redox switching optical, magnetic, and electronic properties. Metalation the 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (N,OLH4) with MnIII affords Mn(N,OL)(DMSO). Structural spectroscopic analysis this show presence MnII centers bridged by N,OL2– ligands, resulting partially from spontaneous ligand-to-metal electron transfer. Upon soaking in solution reductant Cp2Co, Mn(N,OL)(DMSO) undergoes ligand-centered reduction [Mn(N,OL)]−, as revealed suite techniques, including Raman X-ray absorption spectroscopy. The ligand-based engenders dramatic modulation physical properties compound. An electrochromic response, evidenced color change dark green purple is accompanied nearly 40-fold inc...
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Tomi Elovaara, Sayani Majumdar, Hannu Huhtinen, Petriina Paturi, Photoinduced Colossal Magnetoresistance under Substantially Reduced Magnetic Field Advanced Functional Materials. ,vol. 25, pp. 5030- 5037 ,(2015) , 10.1002/ADFM.201502233
Eugenio Coronado, Jose R Galan-Mascaros, Carlos J Gómez-García, Vladimir Laukhin, Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound Nature. ,vol. 408, pp. 447- 449 ,(2000) , 10.1038/35044035
Cyrille Train, Michel Gruselle, Michel Verdaguer, The fruitful introduction of chirality and control of absolute configurations in molecular magnets Chemical Society Reviews. ,vol. 40, pp. 3297- 3312 ,(2011) , 10.1039/C1CS15012J
Amanda E. Baum, Sergey V. Lindeman, Adam T. Fiedler, Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures Chemical Communications. ,vol. 49, pp. 6531- 6533 ,(2013) , 10.1039/C3CC42980F
María D. Manrique-Juárez, Sylvain Rat, Lionel Salmon, Gábor Molnár, Carlos M. Quintero, Liviu Nicu, Helena J. Shepherd, Azzedine Bousseksou, Switchable molecule-based materials for micro- and nanoscale actuating applications: Achievements and prospects Coordination Chemistry Reviews. ,vol. 308, pp. 395- 408 ,(2016) , 10.1016/J.CCR.2015.04.005
M. Mas-Torrent, C. Rovira, J. Veciana, Surface‐Confined Electroactive Molecules for Multistate Charge Storage Information Advanced Materials. ,vol. 25, pp. 462- 468 ,(2013) , 10.1002/ADMA.201201510
Gonzalo Givaja, Pilar Amo-Ochoa, Carlos J. Gómez-García, Félix Zamora, Electrical conductive coordination polymers Chemical Society Reviews. ,vol. 41, pp. 115- 147 ,(2012) , 10.1039/C1CS15092H
Chung-Wei Kung, Timothy Chiaan Wang, Joseph E. Mondloch, David Fairen-Jimenez, Daniel M. Gardner, Wojciech Bury, Jordan Matthew Klingsporn, Jonathan C. Barnes, Richard Van Duyne, J. Fraser Stoddart, Michael R. Wasielewski, Omar K. Farha, Joseph T. Hupp, Metal-organic framework thin films composed of free-standing acicular nanorods exhibiting reversible electrochromism Chemistry of Materials. ,vol. 25, pp. 5012- 5017 ,(2013) , 10.1021/CM403726V
Kevin R. Kittilstved, William K. Liu, Daniel R. Gamelin, Electronic structure origins of polarity-dependent high-TC ferromagnetism in oxide-diluted magnetic semiconductors. Nature Materials. ,vol. 5, pp. 291- 297 ,(2006) , 10.1038/NMAT1616
Kil Sik Min, Antonio G. DiPasquale, James A. Golen, Arnold L. Rheingold, Joel S. Miller, Synthesis, structure, and magnetic properties of valence ambiguous dinuclear antiferromagnetically coupled cobalt and ferromagnetically coupled iron complexes containing the chloranilate(2-) and the significantly stronger coupling chloranilate(*3-) radical trianion. Journal of the American Chemical Society. ,vol. 129, pp. 2360- 2368 ,(2007) , 10.1021/JA067208Q